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Synthesis and Characterization of Nano Silica Supported Tungstophosphoric Acid: An Efficient, Reusable Heterogeneous Catalyst for the Synthesis of Azlactones

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Abstract

A rapid and scale up protocol for the synthesis of azlactones by the Erlenmeyer method under solvent-free conditions was developed. Tungstophosphoric acid supported on nano-silica, TPA@nano-SiO2 was used as a heterogeneous catalyst for the synthesis of a wide range of azlactone derivatives. The catalyst was characterized by physicochemical measurements. The procedure was simple and permitted the quantitative isolation of products and catalyst under thermal conditions. The recycled catalyst was reused more than 5-times without loss of catalytic activity.

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Acknowledgments

The support of this work by the research Council of the University of Isfahan is acknowledged.

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Authors and Affiliations

  1. Catalysis Division, Department of Chemistry, University of Isfahan, 81746-73441, Isfahan, Iran

    Banafshe Samani Ghaleh Taki, Valiollah Mirkhani, Iraj Mohammadpoor-Baltork, Majid Moghadam, Shahram Tangestaninejad, Mahbubeh Rostami & Ahmad Reza Khosropour

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  1. Banafshe Samani Ghaleh Taki
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  2. Valiollah Mirkhani
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  3. Iraj Mohammadpoor-Baltork
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  4. Majid Moghadam
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  5. Shahram Tangestaninejad
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  6. Mahbubeh Rostami
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  7. Ahmad Reza Khosropour
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Correspondence to Valiollah Mirkhani or Majid Moghadam.

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Samani Ghaleh Taki, B., Mirkhani, V., Mohammadpoor-Baltork, I. et al. Synthesis and Characterization of Nano Silica Supported Tungstophosphoric Acid: An Efficient, Reusable Heterogeneous Catalyst for the Synthesis of Azlactones. J Inorg Organomet Polym 23, 758–765 (2013). https://doi.org/10.1007/s10904-012-9810-9

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