Abstract
It is well known that poor wettability at the interface between the Al matrix and the reinforcing phase is a technical bottleneck in the development of aluminum matrix composites. A nitrogen-induced self-forming Al composite (NISFAC) process was developed, which is a novel concept of a composite manufacturing process that does not require vacuum or external pressure. This process employs an exothermic reaction accompanying the nitridation of Al, and the heat dissipated from the reaction enables the local melting and self-sintering of the Al powder. In this study, X-ray photoelectron spectroscopy (XPS) analysis was employed to investigate the compositional changes in monolithic SiC particles and the Al/SiC mixture during heating at 700 °C for 1 h in air, argon, and nitrogen atmospheres, respectively. In addition, XPS results were used to examine the mechanism for the surface modification of Al and SiC particles during the NISFAC process and to understand why self-sintering only occurs in a nitrogen atmosphere.
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Gholipour V, Shamanian M, Ashrafi A, Maleki A (2021) Development of aluminum-nanoclaycomposite by using powder metallurgy and hot extrusion process. Met Mater Int 27:3681. https://doi.org/10.1007/s12540-020-00791-w
K Shah (2016) BCC Research, http://www.bccresearch.com/market-research/advanced-materials/metal-matrix-composites-market-report-avm012e.html. 28 July 2017
Taherzadeh Mousavian R, Behnamfard S, Heidarzadeh A, Taherkhani K, Azari Khosroshahi R, Brabazon D (2021) Incorporation of SiC ceramic nanoparticles into the aluminum matrix by a novel method: production of a metal matrix composite. Met Mater Int 27:2968. https://doi.org/10.1007/s12540-019-00604-9
Chawla N, Chawla K (2006) Metal-matrix composites in ground transportation. JOM 58:67. https://doi.org/10.1007/s11837-006-0231-5
Jang H, Kim S-H, Lee N, Cha P-R, Ahn J-P, Choi H, Lee K-B (2022) Mechanism for self-formation of Al matrix composites using nitridation-induced manufacturing processes. J Mater Res Technol online published. https://doi.org/10.1016/j.jmrt.2022.03.130
Kim D-Y, Cha P-R, Nam H-S, Choi H-J, Lee K-B (2020) Effect of material and process variables on characteristics of nitridation-induced self-formed aluminum matrix composites—part 1: effect of reinforcement volume fraction, size, and processing temperatures. Materials 13:1309. https://doi.org/10.3390/ma13061309
Kim D-Y, Cha P-R, Nam H-S, Choi H-J, Lee K-B (2020) Effect of Material and process variables on characteristics of nitridation-induced self-formed aluminum matrix composites—part 2: effect of nitrogen flow rates and processing temperatures. Materials 13:1213. https://doi.org/10.3390/ma13051213
KB Lee, JP Ahn, H Choi (2018) U.S. Patent 10094006, 9 October 2018
Lee K-B, Kim S-H, Kim D-Y, Cha P-R, Kim H-S, Choi H-J, Ahn J-P (2019) Aluminum matrix composites manufactured using nitridation-induced self-forming process. Sci Rep 9:1. https://doi.org/10.1038/s41598-019-56802-3
Sreemany M, Ghosh T, Pai B, Chakraborty M (1998) XPS studies on the oxidation behavior of SiC particles. Mater Res Bull 33:189. https://doi.org/10.1016/S0025-5408(97)00222-5
Ávila A, Montero I, Galan L, Ripalda JM, Levy R (2001) Behavior of oxygen doped SiC thin films: an x-ray photoelectron spectroscopy study. J Appl Phys 89:212. https://doi.org/10.1063/1.1332796
Lee WJ, Li C, Burke N, Patel J, Wilson M, Gerdes K (2014) Heat treatment of 6H-SiC under different gaseous environments. Ceram Int 40:4149. https://doi.org/10.1016/j.ceramint.2013.08.071
Ramis G, Quintard P, Cauchetier M, Busca G, Lorenzelli V (1989) Surface chemistry and structure of ultrafine silicon carbide: an FT-IR study. J Am Ceram Soc 72:1692. https://doi.org/10.1111/j.1151-2916.1989.tb06304.x
Taylor T (1989) The surface composition of silicon carbide powders and whiskers: an XPS study. J Mater Res 4:189. https://doi.org/10.1557/JMR.1989.0189
Wang PS, Hsu S, Wittberg T (1991) Oxidation kinetics of silicon carbide whiskers studied by X-ray photoelectron spectroscopy. J Mater Sci 26:1655. https://doi.org/10.1007/BF00544678
Miyoshi K, Buckley DH (1982) XPS, AES and friction studies of single-crystal silicon carbide. Appl Surf Sci 10:357. https://doi.org/10.1016/0378-5963(82)90167-2
Rahaman MN, Boiteux Y, De Jonghe LC (1985) Surface characterization of silicon nitride and silicon carbide powders. Am Ceram Soc Bull 65:1171
Tamayo A, Rubio F, Mazo MA, Rubio J (2018) Further characterization of the surface properties of the SiC particles through complementarity of XPS and IGC-ID techniques. Boletín de la Sociedad Española de Cerámica y Vidrio 57:231. https://doi.org/10.1016/j.bsecv.2018.04.003
Gomez E, Gomez-Acebo T, Echeberria J, Iturriza I, Castro F (1994) Nitridation of SiC for the production of SiC-Si3N4 nanocomposites. J Eur Ceram Soc 14:411. https://doi.org/10.1016/0955-2219(94)90079-5
Oh S, Cornie J, Russell K (1989) Wetting of ceramic particulates with liquid aluminum alloys: part II. Study of wettability. Metall Trans A 20:533. https://doi.org/10.1007/BF02653933
Cong XS, Shen P, Wang Y, Jiang Q (2014) Wetting of polycrystalline SiC by molten Al and Al-Si alloys. Appl Surf Sci 317:140. https://doi.org/10.1016/j.apsusc.2014.08.055
Hauert R, Patscheider J, Tobler M, Zehringer R (1993) XPS investigation of the aC: H/Al interface. Surf Sci 292:121. https://doi.org/10.1016/0039-6028(93)90395-Z
Gnecco F, Beccaria A (1999) Corrosion behaviour of Al-Si/SiC composite in sea water. Brit Corros J 34:57. https://doi.org/10.1179/bcj.1999.34.1.57
Wang A-q, H-d Guo M, Li J-P, Ma D-q (2017) Optimization of SiCp surface and interface structure of SiCp/A390 composites. Adv Eng Res 100:646. https://doi.org/10.2991/icmeim-17.2017.110
Ibrahim I, Mohamed F, Lavernia E (1991) Particulate reinforced metal matrix composites—a review. J Mater Sci 26:1137. https://doi.org/10.1007/BF00544448
Kovacich J, Kasperkiewicz J, Lichtman D, Aita C (1984) Auger electron and x-ray photoelectron spectroscopy of sputter deposited aluminum nitride. J Appl Phys 55:2935. https://doi.org/10.1063/1.333335
Cho Y, Kim Y, Weber E, Ruvimov S, Liliental-Weber Z (1999) Chemical and structural transformation of sapphire (Al2O3) surface by plasma source nitridation. J Appl Phys 85:7909. https://doi.org/10.1063/1.370606
Soares GV, Bastos KP, Pezzi RP et al (2004) Nitrogen bonding, stability, and transport in AlON films on Si. Appl Phys Lett 84:4992. https://doi.org/10.1063/1.1763230
Rosenberger L, Baird R, McCullen E, Auner G, Shreve G (2008) XPS analysis of aluminum nitride films deposited by plasma source molecular beam epitaxy. Surf Interface Anal 40:1254. https://doi.org/10.1002/sia.2874
Sharma N, Ilango S, Dash S, Tyagi A (2017) X-ray photoelectron spectroscopy studies on AlN thin films grown by ion beam sputtering in reactive assistance of N+/N2+ ions: substrate temperature induced compositional variations. Thin Solid Films 636:626. https://doi.org/10.1016/j.tsf.2017.07.006
Motamedi P, Cadien K (2014) XPS analysis of AlN thin films deposited by plasma enhanced atomic layer deposition. Appl Surf Sci 315:104. https://doi.org/10.1016/j.apsusc.2014.07.105
Kim S-H, Noh J-H, Ahn J-P et al (2015) Effects of surface oxide on the nitridation behavior of aluminum particles. Metall Mater Trans A 46:496. https://doi.org/10.1007/s11661-014-2604-7
Acknowledgements
This research was supported by the National Research Foundation of Korea (NRF) grant funded by the Korea government (NRF-2017R1A2B4005564, NRF-2020R1I1A1A01057647, NRF-2021M3H4A1A04092462).
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Kim, J., Nayak, K.C., Lee, N. et al. Surface modification of aluminum and silicon carbide during the nitrogen-induced self-forming Al composite (NISFAC) manufacturing process. J Mater Sci 57, 18025–18036 (2022). https://doi.org/10.1007/s10853-022-07240-6
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DOI: https://doi.org/10.1007/s10853-022-07240-6