Skip to main content
Log in

Influence of Fly Ash on Geotechnical Behaviour of Red Mud: A Micro-mechanistic Study

  • Original Paper
  • Published:
Geotechnical and Geological Engineering Aims and scope Submit manuscript

Abstract

The disposal of highly alkaline and hazardous bauxite residue mud generated from the Bayer process in the alumina industry leads to the serious environmental impact on natural resources. Effective and bulk utilization of red mud needs to be done to minimize an adverse impact on environment. The present study contracts to explore the possible utilization of red mud as a geomaterial by modifying its properties with fly ash (Class ‘F’). Detailed geotechnical properties (plasticity characteristics, compaction characteristics, swell index and Unconfined compressive strength (UCS)), physicochemical properties (pH and electrical conductivity) and micro-analyses (XRD, SEM, EDAX and FTIR) have been performed in the red mud amended with varying fly ash content up to 80%. The characterization of red mud demonstrates the higher value of specific gravity, liquid limit, optimum water content (OWC), maximum dry density (ρdmax), pH value, and electrical conductivity than that of the same of fly ash. Further, the amendment with various fly ash content has observed a significant effect on the plasticity and compaction characteristics of the red mud. The results show a significant reduction in liquid limit, plastic limit, OWC and ρdmax of red mud with an increase in fly ash content. Ultimate increase in the UCS of red mud is observed at its substitution with 15% fly ash which can be considered as an Optimum Fly Ash Content (OFC) from strength point of view. Further, experimental results are elucidated through physicochemical and microanalyses.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12
Fig. 13

Similar content being viewed by others

References

  • Aldaood A, Bouasker M, Al-Mukhtar M (2014) Geotechnical properties of lime-treated gypseous soils. Appl Clay Sci 88:39–48

    Google Scholar 

  • Al-Mukhtar M, Khattab S, Alcover JF (2012) Microstructure and geotechnical properties of lime–treated expansive clayey soil. Eng Geol 139:17–27

    Google Scholar 

  • Bureau of Indian Standards (first revision) IS 2720 (Part 10) (1973) Methods of test for soils: determination of unconfined compressive strength. New Delhi India.

  • Bureau of Indian Standards (first revision) IS 2720 (Part 6) (1972) Methods of test for soils: determination of shrinkage factors. New Delhi India.

  • Bureau of Indian Standards (second revision) IS 2720, (Part 3/Set 1) (1980) Methods of test for soils: Determination of specific gravity. New Delhi India.

  • Bureau of Indian Standards (second revision) IS 2720, (Part 5) (1985) Methods of test for soils: Determination of liquid limit and plastic limit. New Delhi India.

  • Bureau of Indian standards IS 1970 (Reaffirmed 1987) (1970) Indian standard classification and identification of soils for general engineering purposes. New Delhi.

  • Bureau of Indian standards IS 2720 (Part 4) (1985) Methods of test for soils: grain size analysis. New Delhi India.

  • Bureau of Indian Standards IS 2720, (Part 40) (1977) Methods of test for soils: determination of free swell index of soil. New Delhi India.

  • Çoruh S, Ergun ON (2010) Use of fly ash, phosphogypsum and red mud as a liner material for the disposal of hazardous zinc leach residue waste. J Hazard Mater 173(1–3):468–473

    Google Scholar 

  • Das B (1994) Principles of geotechnical engineering, 3rd edn. PWS-Kent Publishing Company, Boston

    Google Scholar 

  • Das SN, Thakur RS, Ray HS (1998) Red mud pollution problems: some observations. In: Bandopadhyay A, Goswami NG, Rao PR (eds) Environmental and waste management. NMI, Jamshedpur, pp 11–16. (ISSN: 0971–9407)

  • Das SK, Rout SK, Sahoo T (2013) Design of high embankment using red mud. Rev Road Road Transp Dev Indian Highways 41:27–34

    Google Scholar 

  • Dash SK, Hussain M (2012) Lime stabilization of soils: reappraisal. J Mater Civ Eng 24(6):707–714

    Google Scholar 

  • Davis JA, Kent DB (1990) Surface complexation models in aqueous geochemistry in mineral-water interface geochemistry. Rev Mineral 23:160–177

    Google Scholar 

  • Deelwal K, Dharavath K, Kulshreshtha M (2014) Evaluation of characteristic properties of red mud for possible use as a geotechnical material in civil construction. Int J Adv Eng Technol 7(3):1053

    Google Scholar 

  • Gelencsér A, Kováts N, Turóczi B, Rostási Á, Hoffer A, Imre K, Nyiró-Kósa I, Csákberényi-Malasics D, Tóth Á, Czitrovszky A, Nagy A, Nagy S, Ács A, Kovács A, Ferincz Á, Hartyáni Z, Pósfai M (2011) The red mud accident in Ajka (Hungary): characterization and potential health effects of fugitive dust. Environ Sci Technol 45:1608–1615. https://doi.org/10.1021/es104005r

    Article  Google Scholar 

  • Giannopoulou I, Dimas D, Maragkos I, Panias D (2009) Utilization of metallurgical solid by-products for the development of inorganic polymeric construction materials. Global NEST J 11(2):127–136

    Google Scholar 

  • Göktepe AB, Sezer A, Sezer GI, Ramyar K (2008) Classification of time-dependent unconfined strength of fly ash treated clay. Constr Build Mater 22(4):675–683

    Google Scholar 

  • Gore M S (2015) Geotechnical characterization of bauxite residue (red mud). Thesis Doctor of Philosophy the University of Texas Austin TX.

  • Guo J, Wang R, Tjiu WW, Pan J, Liu T (2012) Synthesis of Fe nanoparticles@ graphene composites for environmental applications. J Hazard Mater 225:63–73

    Google Scholar 

  • Hajela RB, Gupta RG, Goel RK (1989) Disposal of solid wastes-red mud and fly-ash in the production of heavy clay products. Int J Environ Stud 33(1–2):125–132

    Google Scholar 

  • He AP, Hu ZL, Cao DG, Zeng JM, Wu BL, Wang LJ (2014) Extraction of valuable metals from red mud. Adv Mater Res 881:667–670

    Google Scholar 

  • International Aluminium Institute (2015) Bauxite Residue Management: Best Practice.

  • JCPDS (Joint Committee on Powder Diffraction Standards) (1999) Index to the powder diffraction file. International Centre for Diffraction Data, Newtown Square

    Google Scholar 

  • Jha AK, Sivapullaiah PV (2015a) Mechanism of improvement in the strength and volume change behaviour of lime stabilized soil. Eng Geol 198:53–64

    Google Scholar 

  • Jha AK, Sivapullaiah PV (2015b) Susceptibility of strength development by lime in gypsiferous soil—a micro mechanistic study. Appl Clay Sci 115:39–50

    Google Scholar 

  • Jha AK, Sivapullaiah PV (2016a) Gypsum-induced volume change behaviour of stabilized expansive soil with fly ash-lime. Geotech Test J 39(3):391–406

    Google Scholar 

  • Jha AK, Sivapullaiah PV (2016b) Role of gypsum on microstructure and strength of soil. Environ Geotech ICE 3(2):78–89

    Google Scholar 

  • Jha AK, Sivapullaiah PV (2017) Physical and strength development in lime treated gypseous soil with fly ash—micro-analyses. Appl Clay Sci 145:17–27

    Google Scholar 

  • Jha AK, Sivapullaiah PV (2018) Potential of fly ash to suppress the susceptible behaviour of lime-treated gypseous soil. Soils Found 58(3):654–665

    Google Scholar 

  • Kalkan E (2006) Utilization of red mud as a stabilization material for the preparation of clay liners. Eng Geol 87(3–4):220–229

    Google Scholar 

  • Kehagia F (2008) An innovative geotechnical application of bauxite residue. Elect J Geotech Eng 13(G):1–9

    Google Scholar 

  • Kumar A, Walia BS, Bajaj A (2007) Influence of fly ash, lime, and polyester fibers on compaction and strength properties of expansive soil. J Mater Civ Eng 19(3):242–248

    Google Scholar 

  • Kumar Phani BR, Sharma RS (2004) Effect of fly ash on engineering properties of expansive soils. J Geotech Geoenviron Eng 130(7):764–767

    Google Scholar 

  • Kumar S, Prasad A (2017) Parameters controlling strength of red mud-lime mix. Eur J Environ Civil Eng. https://doi.org/10.1080/19648189.2017.1304280

    Article  Google Scholar 

  • Kushwaha SS, Kishan D (2016) Stabilization of red mud by lime and gypsum and investigating its possible use in geoenvironmental engineering. In: Geo-Chicago pp 978–988.

  • Langmuir D (1997) Aqueous environmental geochemistry. Prentice-Hall, Englewood Cliffs

    Google Scholar 

  • Li LY (1998) Properties of red mud tailings produced under varying process conditions. J Environ Eng 124(3):254–264

    Google Scholar 

  • Little D N (1995) Stabilization of pavement subgrades and base courses with lime. Kendall Hunt Publishing Company Iowa USA (by National Lime Association).

  • Liu Z, Li H (2015) Metallurgical process for valuable elements recovery from red mud—a review. Hydrometallurgy 155:29–43

    Google Scholar 

  • Liu RX, Poon CS (2016) Utilization of red mud derived from bauxite in self-compacting concrete. J Clean Prod 112:384–391

    Google Scholar 

  • Liu X, Zhang N (2011) Utilization of red mud in cement production: a review. Waste Manage Res 29:1053–1063

    Google Scholar 

  • Mohan S, Gandhimathi R (2009) Removal of heavy metal ions from municipal solid waste leachate using coal fly ash as an adsorbent. J Hazard Mater 169(1–3):351–359

    Google Scholar 

  • Molineux CJ, Newport DJ, Ayati B, Wang C, Connop SP, Green JE (2016) Bauxite residue (red mud) as a pulverized fuel ash substitute in the manufacture of lightweight aggregate. J Clean Prod 112:401–408

    Google Scholar 

  • Mukiza E, Zhang L, Liu X, Zhang N (2019) Utilization of red mud in road base and subgrade materials: a review. Res Conserv Recycl 141:187–199

    Google Scholar 

  • Newson T, Dyer T, Adam C, Sharp S (2006) Effect of structure on the geotechnical properties of bauxite residue. J Geotech Geoenviron Eng 132(2):143–151

    Google Scholar 

  • Nikraz HR, Bodley AJ, Cooling DJ, Kong PYL, Soomro M (2007) Comparison of physical properties between treated and untreated bauxite residue mud. J Mater Civ Eng 19(1):2–9

    Google Scholar 

  • O'Flaherty CA, David HT, Davidson DT (1961) Relationship between the California bearing ratio and the unconfined compressive strength of sand-cement mixtures. Proc Iowa Acad Sci 68(1):341–356

    Google Scholar 

  • Parekh BK, Goldberger WM (1976) An assessment of technology for possible utilization of bayer process muds. US Environmental Protection Agency Washington DC USA EPA/600/2-76/301: 154.

  • Park SJ, Jun BR (2005) Improvement of red mud polymer-matrix nano-composites by red mud surface treatment. J Colloid Interface Sci 284:204–209

    Google Scholar 

  • Patel S, Pal BK (2015) Current status of an industrial waste: red mud an overview. Int J Latest Technol Eng Manag Appl Sci 4(8):1–16

    Google Scholar 

  • Pontikes Y, Nikolopoulos P, Angelopoulos GN (2007) Thermal behaviour of clay mixtures with bauxite residue for the production of heavy-clay ceramics. J Eur Ceram Soc 27:1645–1649

    Google Scholar 

  • Querol X, Alastuey A, Moreno N, Alvarez-Ayuso E, García-Sánchez A, Cama J, Simón M (2006) Immobilization of heavy metals in polluted soils by the addition of zeolitic material synthesized from coal fly ash. Chemosphere 62(2):171–180

    Google Scholar 

  • Ribeiro DV, Labrincha JA, Morelli MR (2012) Effect of the addition of red mud on the corrosion parameters of reinforced concrete. Cem Concr Res 42:124–133

    Google Scholar 

  • Rios CA, Williams CD, Roberts CL (2008) Removal of heavy metals from acid mine drainage (AMD) using coal fly ash, natural clinker and synthetic zeolites. J Hazard Mater 156(1–3):23–35

    Google Scholar 

  • Rout SK, Sahoo T, Das SK (2013) Design of tailing dam using red mud. Central Eur J Eng 3(2):316–328

    Google Scholar 

  • Ruyters S, Mertens J, Vassilieva E, Dehandschutter B, Poffijn A, Smolders E (2011) The red mud accident in Ajka (Hungary): plant toxicity and trace metal bioavailability in red mud contaminated soil. Environ Sci Technol 45:1616–1622. https://doi.org/10.1021/es104000m

    Article  Google Scholar 

  • Sabat AK, Mohanta S (2015) Efficacy of dolime fine stabilized red mud-fly ash mixes as subgrade material. ARPN J Eng Appl Sci 10:5918–5923

    Google Scholar 

  • Samal S, Ray AK, Bandopadhyay A (2013) Proposal for resources, utilization and processes of red mud in India—a review. Int J Miner Process 118:43–55

    Google Scholar 

  • Sivapullaiah PV, Sitharam TG, Rao KS (1987) Modified free swell index for clays. Geotech Test J 10(2):80–85

    Google Scholar 

  • Sivapullaiah PV, Sridharan A, Raju KVB (2000) Role of amount and type of clay in the lime stabilization of soils. Proc ICE Ground Improve 4(1):37–45

    Google Scholar 

  • Smičiklas I, Smiljanić S, Perić-Grujić A, Šljivić-Ivanović M, Mitrić M, Antonović D (2014) Effect of acid treatment on red mud properties with implications on Ni (II) sorption and stability. Chem Eng J 242:27–35

    Google Scholar 

  • Smirnov DI, Molchanova TV (1997) The investigation of sulfuric acid sorption recovery of scandium and uranium from the red mud of alumina production. Hydrometallurgy 45:249–259

    Google Scholar 

  • Somogyi F, Gray D H (1977) Engineering properties affecting disposal of red muds. In: Geotechnical practice for disposal of solid waste materials ASCE pp 1–22.

  • Sridharan A, Sivapullaiah PV (2005) Mini compaction test apparatus for fine grained soils. Geotech Test J 28(3):240–246

    Google Scholar 

  • Sridharan A, Rao SM, Murthy NS (1985) Free swell index of soils: a need for redefinition. Indian Geotech J 15(2):94–99

    Google Scholar 

  • Sutar H, Mishra SC, Sahoo SK, Maharana H (2014) Progress of red mud utilization: an overview. Am Chem Sci J 4:255–279

    Google Scholar 

  • Swanepoel JC, Strydom CA (2002) Utilisation of fly ash in a geopolymeric material. Appl Geochem 17(8):1143–1148

    Google Scholar 

  • Tsakiridis PE, Agatzini-Leonardou S, Oustadakis P (2004) Red mud addition in the raw meal for the production of Portland cement clinker. J Hazard Mater 116:103–110. https://doi.org/10.1016/j.jhazmat.2004.08.002

    Article  Google Scholar 

  • Vick SG (1990) Risk based approach to seismic stability and inundation hazard for upstream tailings dams. In Proceedings of international symposium on safety and Rehabilitation of tailings dams. Australia: ICOLD.

  • Wang P, Liu DY (2012) Physical and chemical properties of sintering red mud and bayer red mud and the implications for beneficial utilization. Materials 5(10):1800–1810

    Google Scholar 

  • Xue S, Zhu F, Kong X, Wu C, Huang L, Huang N, Hartley W (2016) A review of the characterization and revegetation of bauxite residues (Red mud). Environ Sci Pollut Res 23(2):1120–1132

    Google Scholar 

  • Yang JK, Fan C, Hou J, Xiao B, Liu W (2006) Engineering application of basic level materials of red mud high level pavement. Chin Mun Eng 123:7–9

    Google Scholar 

  • Zhang N, Liu X, Sun H, Li L (2011) Pozzolanic behaviour of compound-activated red mud-coal gangue mixture. Cem Concr Res 41(3):270–278

    Google Scholar 

  • Zhang M, Zhao M, Zhang G, Mann D, Lumsden K, Tao M (2016) Durability of red mud-fly ash based geopolymer and leaching behaviour of heavy metals in sulfuric acid solutions and deionized water. Constr Build Mater 124:373–382

    Google Scholar 

  • Zhong L, Zhang Y, Zhang Y (2009) Extraction of alumina and sodium oxide from red mud by a mild hydro-chemical process. J Hazard Mater 172(2–3):1629–1634

    Google Scholar 

Download references

Acknowledgements

The authors would like to thanks and acknowledge to Research and Development (R & D) division of Manipal University Jaipur (MUJ) for financial support under SEED grant [MUJ/REGR/1435/07] to complete the present work. Authors also thanks to department of basic sciences, MUJ for allowing to perform FTIR analysis of samples. Authors appreciate and, would also like to acknowledge reviewers/editor for their valuable comments/remarks/suggestions which support significantly in improving the quality of manuscript.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Arvind Kumar Jha.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Jha, A.K., Kumar, D. & Sivapullaiah, P.V. Influence of Fly Ash on Geotechnical Behaviour of Red Mud: A Micro-mechanistic Study. Geotech Geol Eng 38, 6157–6176 (2020). https://doi.org/10.1007/s10706-020-01425-z

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10706-020-01425-z

Keywords

Navigation