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A multiple hollow fibre liquid-phase microextraction method for the determination of halogenated solvent residues in olive oil

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Abstract

The present paper describes a method based on the extraction of analytes by multiple hollow fibre liquid-phase microextraction and detection by ion-trap mass spectrometry and electron capture detectors after gas chromatographic separation. The limits of detection are in the range of 0.13–0.67 μg kg−1, five orders of magnitude lower than those reached with the European Commission Official method of analysis, with three orders of magnitude of linear range (from the quantification limits to 400 μg kg−1 for all the analytes) and recoveries in fortified olive oils in the range of 78–104 %. The main advantages of the analytical method are the absence of sample carryover (due to the disposable nature of the membranes), high enrichment factors in the range of 79–488, high throughput and low cost. The repeatability of the analytical method ranged from 8 to 15 % for all the analytes, showing a good performance.

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References

  1. Commission Regulation (EEC) (1991). Official Journal of the European Union L248 No 2568/1991: 48. Amended by (2003) L295 No. 1989/2003:57

  2. Arrebola FJ, González-Rodríguez MJ, Garrido Frenich A, Marín-Juan A, Martínez Vidal JL (2005) Anal Chim Acta 552:60–66

    Article  CAS  Google Scholar 

  3. Manso J, Gómez-Ariza JL, García-Barrera T (2011) J Chromatogr A 1218:7923–7935

    Article  CAS  Google Scholar 

  4. Ezquerro Ó, Pons B, Tena MT (2003) J Chromatogr A 999:155–164

    Article  CAS  Google Scholar 

  5. Wen X, Tu C, Lee HK (2004) Anal Chem 76:228–232

    Article  CAS  Google Scholar 

  6. González AG, Herrador MA, Asuero AG (2006) Accred Qual Assur 11:256–258

    Article  Google Scholar 

Download references

Acknowledgments

This work was supported by the projects P08-FQM-3554 and P09-FQM-4659 from “Consejería de Innovación, Ciencia y Empresa” (Andalusian Government) and the project CTM2009-12858-C02-01 from the “Ministerio de Ciencia e Innovación”. J. Manso thanks the Consejería de Innovación Ciencia y Empresa for a predoctoral scholarship.

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Authors and Affiliations

  1. Department of Chemistry and Materials Science, Faculty of Experimental Sciences, University of Huelva, Campus de El Carmen, 21007, Huelva, Spain

    J. Manso, T. García-Barrera & J. L. Gómez-Ariza

  2. Research Center on Health and Environment (CYSMA), University of Huelva, Campus de El Carmen, 21007, Huelva, Spain

    J. Manso, T. García-Barrera & J. L. Gómez-Ariza

  3. International Campus of Excellence on Agrofood (ceiA3), University of Huelva, Huelva, Spain

    J. Manso, T. García-Barrera & J. L. Gómez-Ariza

  4. Department of Analytical Chemistry, University of Seville, 41012, Seville, Spain

    A. G. González

Authors
  1. J. Manso
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  2. T. García-Barrera
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  3. J. L. Gómez-Ariza
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  4. A. G. González
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Corresponding author

Correspondence to T. García-Barrera.

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Manso, J., García-Barrera, T., Gómez-Ariza, J.L. et al. A multiple hollow fibre liquid-phase microextraction method for the determination of halogenated solvent residues in olive oil. Anal Bioanal Chem 406, 1567–1571 (2014). https://doi.org/10.1007/s00216-013-7552-3

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  • DOI: https://doi.org/10.1007/s00216-013-7552-3

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