Abstract
The aim of this study was to examine the fate of quaternary herbicides in soil deposits derived from erosion of vineyard-devoted soils. Herbicide occurrence in the crop soils was due to the farmer application inputs. Special attention should be paid to the presence of paraquat (PQ) in the studied vineyard-devoted soils. The major factor governing the sorption of PQ was the solid state organic fraction with the clay mineral content also making a significant contribution. The mobilization and transport of quats-enriched soil particles may generate downslope and downstream environmental problems that mainly affect detritivore ecology.
Similar content being viewed by others
References
Barceló D (1993) In: Barceló D (ed) Environmental analysis techniques, applications and quality assurance. Elsevier, Amsterdam, pp 149
Chichila TMP, Walters SM (1991) Liquid chromatographic determination of paraquat and diquat in crops using a silica column with aqueous ionic mobile phase. J AOAC Int 74(6):961–967
De Liñán y Vicente C (1997a) Farmacología Vegetal. Compendio de las materias activas más interesantes en fitopatología. Su toxicología y empleo, Agrotécnicas, Madrid
De Liñán y Vicente C (1997b) Vademecum de productos fitosanitarios y nutricionales. Agrotécnicas, Madrid
Dunjó G, Pardini G, Gispert M (2003) Land use change effects on abandoned terraced soils in a Mediterranean catchment, NE Spain. Catena 52:23–37
European Commission (2006) Wine: economy of the sector. Directorate General for Agriculture and Rural Development. Brussels, Belgium, pp 1–154
Galcerán MT, Carneiro MC, Puignou L (1994) Capillary electrophoresis of quaternary ammonium ion herbicides: paraquat, diquat and difenzoquat. Chromatographia 39:581–586
Haag WR, Yao CCD (1992) Rate constants for reaction of hydroxyl radicals with several drinking water contaminants. Environ Sci Technol 26:1005–1013
Kenaga EE (1980) Predicted bioconcentration factors and soil sorption coefficients of pesticides and other chemicals. Ecotox Environ Safe 4:26–38
Kosmas C, Danalatos N, Cammeraat LH, Chabart M, Diamantopoulos J, Farand R, Gutierrez L, Jacob A, Marques H, Martinez-Fernandez J, Mizara A, Moustakas N, Nicolau JM, Oliveros C, Pinna G, Puddu R, Puigdefábregas J, Roxo M, Simao A, Stamou G, Tomasi N, Usai N, Vacca A (1997) The effect of land use of runoff and soil erosion rates under Mediterranean conditions. Catena 29:45–59
Koulouri M, Giourga C (2007) Land abandonment and slope gradient as key factors of soil erosion in Mediterranean terraced lands. Catena 69:274–281
Martínez-Casasnovas JA, Ramos MC (2006) The cost of soil erosion in vineyard fields in the Penedés-Anoia Region (NE Spain). Catena 68:194–199
McCall PJ, Laskowski DA, Swann RL, Dishburger HJ (1980) Measurement of sorption coefficients or organic chemicals and their use in environmental fate analysis. Proceedings of symposium, association of official analytical chemists, 94th annual meeting, 1980, Washington
Pateiro-Moure M, Pérez-Novo C, Arias-Estévez M, López-Periago E, Martínez-Carballo E, Simal-Gándara J (2007) Influence of copper on the adsorption and desorption of paraquat, diquat and difenzoquat in vineyard acid soils. J Agric Food Chem 55:6219–6226
Pond SM (1998) Goldfrank’s-toxicologic emergencies. In: LR Goldfrank, NE Flomenbaum, NA Lewin, RS Weisman, MA Howland, R Hoffman (eds) Appelton & Lange, Stanford, pp 1475
Riley D, Tucker BV, Wilkinson W (1976) Biological unavailability of bound paraquat residues in soil. In: Kaufman DD, Still GG, Paulson GD, Vandal SK (eds) Bound and conjugated pesticide residues. ACS symposium series 29, American Chemical Society, Washington, DC, pp 301–353
Roberts TR, Dyson JS, Lane MCG (2002) Deactivation of the biological activity of paraquat in the soil environment – a review. J Agric Food Chem 50:3623–3631
Rodríguez-Cruz S, Andrades MS, Sánchez-Camazano M, Sánchez-Martín MJ (2007) Relationship between the adsorption capacity of pesticides by wood residues and the properties of woods and pesticides. Environ Sci Technol 41:3613–3619
Rytwo G, Tavasi M (2003) Addition of a monovalent cationic pesticide to improve efficacy of bipyridyl herbicides in Hulah valley soils. Pest Manag Sci 59:1265–1270
Rytwo G, Tropp D (2001) The use of clay–organic interactions to improve efficacy of contact herbicides: addition of monovalent organocations to diquat. Appl Clay Sci 18:327–333
Spark KM, Swift RS (2002) Effect of soil composition and dissolved organic matter on pesticide sorption. Sci Total Environ 298:147–161
Tsakis AM, Perakis K, Koumantakis E (1996) Experience with acute paraquat poisoning in Crete. Vet Hum Toxicol 38:113–117
US-EPA (1994) Reregistration elegibility decision (RED) DFQ. United States Environmental Protection Agency, EPA 738-R-94-018
Weber JB, Best JA, Gonese JA (1993) Bioavailability and bioactivity of sorbed organic chemicals. In: SSSA (ed) Sorption and degradation of pesticides and organic chemicals in soil. Soil Science Society of America, Madison, pp 153
Wetzel RG (2001) Limnology: lake and river ecosystems, 3rd edn. Academic Press, pp 700
Zen JM, Jeng SH, Chen HJ (1996) Determination of paraquat by square wave voltammetry at a perfluorosulfonated ionomer/clay modified electrode. Anal Chem 68:498–502
Acknowledgements
This work was supported by Xunta de Galicia under contract PGIDIT05PXIB38302PR and by Spain’s Ministry of Science and Technology under contract AGL2007–62075. Award of a Ramón y Cajal contract to E.L-P., and a Parga Pondal contract to E.M.-C., is also gratefully acknowledged.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Pateiro-Moure, M., Arias-Estévez, M., López-Periago, E. et al. Occurrence and Downslope Mobilization of Quaternary Herbicide Residues in Vineyard-Devoted Soils. Bull Environ Contam Toxicol 80, 407–411 (2008). https://doi.org/10.1007/s00128-008-9403-z
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s00128-008-9403-z