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Lanthanide metallocenes in homogeneous catalysis

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Organolanthoid Chemistry: Synthesis, Structure, Catalysis

Part of the book series: Topics in Current Chemistry ((TOPCURRCHEM,volume 179))

Abstract

This comprehensive review summarizes recent developments and trends in the use of lanthanide metallocenes in homogeneous catalysis. σ-Alkyl and hydride complexes such as (C5Me5)2LnCH (SiMe3)2 and [(C5Me5)2Ln(μ-H)]2 play a key role as precatalysts in organolanthanide mediated reactions. The design and synthesis of such complexes is outlined first. This is followed by a description of various processes catalyzed by lanthanide metallocenes such as olefin, diene, and alkyne transformations. Olefin transformations include oligomerizations and polymerization as well as a variety of addition reactions. In some instances catalyst activities are exceedingly high as compared to conventional d-transition metal catalysts.

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Authors and Affiliations

  1. Chemisches Institut der Otto-von-Guericke-Universität Magdeburg, Universitätsplatz 2, Gebäude M, 39106, Magdeburg, Germany

    Frank T. Edelmann

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  1. Frank T. Edelmann
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Dedicated to Prof. Walter Schwartr on the occasion of his 65th birthday

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© 1996 Springer-Verlag

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Edelmann, F.T. (1996). Lanthanide metallocenes in homogeneous catalysis. In: Organolanthoid Chemistry: Synthesis, Structure, Catalysis. Topics in Current Chemistry, vol 179. Springer, Berlin, Heidelberg. https://doi.org/10.1007/BFb0015598

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  • DOI: https://doi.org/10.1007/BFb0015598

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  • Print ISBN: 978-3-540-61009-0

  • Online ISBN: 978-3-540-49786-8

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