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Reviews include I. F. Schegolev, Phys. Stat. Sol. (A), 12, 9 (1972); (b). A. N. Bloch, in Energy and Charge Transfer in Organic Semiconductors, edited by K. Masuda and M. Silver (Plenum Press, New York, 1974), p. 159; (c) A. N. Bloch, D. O. Cowan, and T. O. Poehler, in Energy and Charge Transfer in Organic Semiconductors, edited by K. Masuda and M. Silver (Plenum Press, New York, 1974), p. 167; (d) A. F. Garito and A. J. Heeger, Accounts Chem. Res., 7, 232 (1974); (e) A. J. Berlinsky, Contemp. Phys., 17, 331 (1976); (f) D. 0. Cowan, P. Shu, C. Hu, W. Krug, T. Carruthers, T. Poehler, and A. Bloch, in Proceedings of the NATO Conference on the Chemistry and Physics of One-Dimensional Metals, Bolzano, Italy, ed. H. J. Keller (Plenum Press, New York, 1977), in press.
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Perhaps because these interactions are so weak, several distinct crystalline forms of TMTTF-TCNQ have been observed (Refs. 23 and 32). The one described here, though different from that originally reported in Ref. 22, is by far the most prevalent (Ref. 23).
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The 47 K anomaly in the conductivity, though absent in the data of Ref. 13c, has now been observed independently in several laboratories. To our knowledge it was first reported by us (Ref. 72), and separately by P. Horn and D. Guidotti, at the 1976 March meeting of the American Physical Society (Atlanta, Ga.).
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This effect is distinct from the stabilization of the Peierls gap by the softening of intramolecular optical modes suggested by M. J. Rice, C. B. Duke, and N. O. Lipari [Sol. St. Comm., 17, 1089 (1975)].In fact, their calculation is flawed in its assumption that the phases of the intramolecular and intermolecular soft modes are arbitrary. The correct theory [A. Madhukar, Chem. Phys. Lett., 27, 606 (1974)] recognizes that the former modes build up charge around the lattice sites and the latter in the bonding regions; hence the two instabilities compete.
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G. Giulliani, E. Tosatti, and M. P. Tosi, Lett. Nuovo Cimento, 16, 385 (1976).
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Bloch, A.N. (1977). Chemical trends in organic conductors: Stabilization of the nearly one-dimensional metallic state. In: Pál, L., Grüner, G., Jánossy, A., Sólyom, J. (eds) Organic Conductors and Semiconductors. Lecture Notes in Physics, vol 65. Springer, Berlin, Heidelberg. https://doi.org/10.1007/BFb0012387
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