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Chemical trends in organic conductors: Stabilization of the nearly one-dimensional metallic state

  • V. Experimental Investigations on TTF-TCNQ and its Derivatives
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Organic Conductors and Semiconductors

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References

  1. Reviews include I. F. Schegolev, Phys. Stat. Sol. (A), 12, 9 (1972); (b). A. N. Bloch, in Energy and Charge Transfer in Organic Semiconductors, edited by K. Masuda and M. Silver (Plenum Press, New York, 1974), p. 159; (c) A. N. Bloch, D. O. Cowan, and T. O. Poehler, in Energy and Charge Transfer in Organic Semiconductors, edited by K. Masuda and M. Silver (Plenum Press, New York, 1974), p. 167; (d) A. F. Garito and A. J. Heeger, Accounts Chem. Res., 7, 232 (1974); (e) A. J. Berlinsky, Contemp. Phys., 17, 331 (1976); (f) D. 0. Cowan, P. Shu, C. Hu, W. Krug, T. Carruthers, T. Poehler, and A. Bloch, in Proceedings of the NATO Conference on the Chemistry and Physics of One-Dimensional Metals, Bolzano, Italy, ed. H. J. Keller (Plenum Press, New York, 1977), in press.

    Google Scholar 

  2. V. K. S. Shante, A. N. Bloch, D. O. Cowan, W. M. Lee, S. Choi, and M. H. Cohen, Bull. Amer. Phys. Soc., 21, 287 (1976); and to be published.

    Google Scholar 

  3. A. J. Berlinsky, J. F. Carolan, and L. Weiler, Sol. St. Comm., 15, 795 (1974).

    Google Scholar 

  4. See, for example, M. H. Cohen, J. Non-Cryst. Sol., 2, 432 (1970)

    Google Scholar 

  5. Z. G. Soos, Ann. Rev. Phys. Chem., 25, 121 (1974).

    Google Scholar 

  6. P. F. Williams and A. N. Bloch, Phys. Rev., B10, 1097 (1974).

    Google Scholar 

  7. For a review, see F. H. Herbstein, in Perspectives in Structural Chemistry, edited by J. D. Dunitz and J. A. Ibers (Wiley, New York, 1972), Vol. IV, p. 166.

    Google Scholar 

  8. R. E. Peierls, Quantum Theory of Solids (Oxford Press, London, 1955), p. 108.

    Google Scholar 

  9. See, for example, B. I. Halperin, Adv. Chem. Phys., 13, 123 (1966).

    Google Scholar 

  10. L. D. Landau and E. M. Lifschitz, Statistical Physics (Pergamon Press, New York, 1958), p. 482.

    Google Scholar 

  11. J. Ferraris, D. O. Cowan, V. Walatka, and J. H. Perlstein, J. Amer. Chem. Soc., 95, 498 (1973).

    Google Scholar 

  12. A. N. Bloch, D. O. Cowan, K. Bechgaard, R. E. Pyle, and R. H. Banks, Phys. Rev. Lett., 34, 1561 (1975).

    Google Scholar 

  13. S. Etemad, T. Penney, E. M. Engler, B. A. Scott, and P. E. Seiden, Phys. Rev. Lett., 34, 741 (1975)

    Google Scholar 

  14. Y. Tomkiewicz, E. M. Engler, and T. D. Schultz, Phys. Rev. Lett., 35, 456 (1975)

    Google Scholar 

  15. S. Etemad, Phys. Rev., B13, 2254 (1976).

    Google Scholar 

  16. G. Beni, Sol. St. Comm., 15, 269 (1974).

    Google Scholar 

  17. D. J. Scalapino, Y. Imry, and P. Pincus, Phys. Rev., B11, 2042 (1975).

    Google Scholar 

  18. See, for example, P. A. Lee, T. M. Rice, and P. W. Anderson, Phys. Rev. Lett., 31, 462 (1973).

    Google Scholar 

  19. M. H. Cohen, J. A. Hertz, P. M. Horn, and V. K. S. Shante, Int. J. Quant. Chem. Symp., No. 8, 491 (1974).

    Google Scholar 

  20. U. Bernstein, P. M. Chaikin, and P. Pincus, Phys. Rev, Lett., 34, 271 (1975).

    Google Scholar 

  21. T. J. Kistenmacher, T. E. Phillips, and D. O. Cowan, Acta Cryst., B30, 763 (1974)

    Google Scholar 

  22. F. Denoyer, R. Comes, A. F. Garito, and A. J. Heeger, Phys. Rev. Lett., 35, 445 (1975); R. Comes, S, M. Shapiro, G. Shirane, A, F. Garito, and A. J, Heeger, Phys. Rev, Lett., 35, 1518 (1975); S. Kagoshima, H, Anzai,.:. Majimura, and T, Ishigoro, J, Phys. Soc. Japan, 39, 1143 (1975); R, Comes, in Proceedings of the NATO Conference on the Chemistry and Physics of One-Dimensional Metals, Bolzano, Italy, ed. H. J. Keller (Plenum Press, New York, 1977), in press.

    Google Scholar 

  23. A similar interpretation of this material has been conceived independently by M. Weger, Sol. St. Comm. 19, 1149 (1976). See also Refs. 31 and 49.

    Google Scholar 

  24. J. P. Ferraris, T. O. Poehler, A. N. Bloch, and D. O. Cowan, Tet. Lett., 27, 2553 (1976).

    Google Scholar 

  25. T. E. Phillips, T. J. Kistenmacher, A. N. Bloch, J. P. Ferraris, and D. O. Cowan, Acta. Cryst. (in press).

    Google Scholar 

  26. M. A. Butler, J. P. Ferraris, A. N. Bloch, and D. O. Cowan, Chem. Phys. Lett., 24, 600 (1974)

    Google Scholar 

  27. Perhaps because these interactions are so weak, several distinct crystalline forms of TMTTF-TCNQ have been observed (Refs. 23 and 32). The one described here, though different from that originally reported in Ref. 22, is by far the most prevalent (Ref. 23).

    Google Scholar 

  28. K. Bechgaard, D. O. Cowan, and A. N. Bloch, Chem. Comm., 1974, 937.

    Google Scholar 

  29. K. Bechgaard, T. J. Kistenmacher, A. N. Bloch, and D. O. Cowan, Acta, Cryst. (in press).

    Google Scholar 

  30. K. Bechgaard, D. O. Cowan, and A. N. Bloch, Mol. Cryst. and Liq. Cryst., 32, 237 (1976).

    Google Scholar 

  31. T. E. Phillips, T. J. Kistenmacher, A. N. Bloch, and D. O. Cowan, J. C. S. Chem. Comm., 1976, 334 (1976).

    Google Scholar 

  32. T. O. Poehler, unpublished.

    Google Scholar 

  33. L. B. Coleman, M. J. Cohen, D. J. Sandman, F. G. Yamagishi, A. F. Garito, and A. J. Heeger, Sol. St. Commm., 12, 1125 (1973).

    Google Scholar 

  34. T. J. Kistenmacher, T. E. Phillips, D. O. Cowan, J. P. Ferraris, and A. N. Bloch, Acta. Cryst., B32, 539 (1976).

    Google Scholar 

  35. Y. Tomkiewicz, B. A. Scott, L. J. Tao, and R. S. Title, Phys. Rev, Lett., 32, 1363 (1974).

    Google Scholar 

  36. T. O. Poehler, J. Bohandy, A. N. Bloch, and D. O. Cowan, Bull. Amer. Phys., Soc., 21, 287 (1976).

    Google Scholar 

  37. Y. Tomkiewicz, T. D. Shultz, E. M. Engler, A. R. Taranko, and A. N. Bloch, Bull. Amer. Phys. Soc., 21, 287 (1976). See also Ref. 13b.

    Google Scholar 

  38. A. W. Overhauser, Phys. Rev., 89, 689 (1953).

    Google Scholar 

  39. R. J. Elliot, Phys. Rev., 96, 266 (1954).

    Google Scholar 

  40. Y. Yafet, Sol. St. Phys., 14, 1 (1963).

    Google Scholar 

  41. Y. Tomkiewicz, D. Garrod, A. R. Taranko, and A. N. Bloch, preprint.

    Google Scholar 

  42. J. C. Scott, A. F. Garito, and A. J. Heeger, Phys. Rev., B10, 3131 (1974).

    Google Scholar 

  43. S. Etemad, private communication. 42. F. J. DiSalvo, W. A. Reed, F. Hsu, A. N. Bloch, and D. O. Cowan, unpublished.

    Google Scholar 

  44. F. B. Torrance, in Proceedings of the NATO Conference on the Chemistry and Physics of One-Dimensional Metals, Bolzano, Italy, ed. H. J. Keller (Plenum Press, New York, 1977), in press.

    Google Scholar 

  45. P. A. Lee, T. M. Rice, and R. A. Klemm, preprint.

    Google Scholar 

  46. V. J. Emery, in Proceedings of the NATO Conference on the Chemistry and Physics of One-Dimensional Metals, Bolzano, Italy, ed. H. J. Keller (Plenum Press, New York, 1977), in press.

    Google Scholar 

  47. C. Weyl, E. M. Engler, S. Etemad, K. Bechgaard, and G. Jehanno, Sol. St. Comm., 19, 925 (1976).

    Google Scholar 

  48. The data for HMTSF-TCNQ (Ref. 42), first presented at the 1975 March meeting of the American Physical Society (Denver, Colo.), have been essentially reproduced by G. Soda, D. Jerome, M. Weger, K. Bechgaard, and E. Pederson, Sol. St. Comm., 19, (in press); see also Ref. 50a. Our results and interpretation were communicated directly to these authors in early 1976.

    Google Scholar 

  49. T. Carruthers, unpublished.

    Google Scholar 

  50. J. R. Cooper, M. Weger, D. Jerome, D. Lefur, K. Bechgaard, A. N. Bloch, and D. O. Cowan, Sol. St. Comm., 19, 749 (1976).

    Google Scholar 

  51. D. Jerome and H. Weger, Proceedings of the NATO Conference on the Chemistry and Physics of One-Dimensional Metals, Bolzano, Italy, ed. H. J. Keller (Plenum Press, New York, 1977), in press

    Google Scholar 

  52. G. Soda, D. Jerome, M. Weger. J. M. Fabre, and L. Giral, Sol. St. Comm., 18, 1417 (1976).

    Google Scholar 

  53. A. N. Bloch, R. B. Weisman, and C. M. Varma, Phys. Rev. Lett., 28, 753 (1972).

    Google Scholar 

  54. G. A. Thomas, et al., Phys. Rev., B13, 5105 (1976).

    Google Scholar 

  55. Substantial residual conductivities as T → O have also been observed in HMTSF-TNAP (Ref. 12) and in the halides of tetrathiatetracene, TTT (E. Perez-Albuerne, work presented at the 1976 March meeting of the American Physical Society [Atlanta, Ga.]; I. F. Schegolev, this volume.)

    Google Scholar 

  56. R. L. Greene, unpublished.

    Google Scholar 

  57. R. P. Groff, A. Suna, and R. E. Merrifield, Phys. Rev. Lett., 33, 418 (1974).

    Google Scholar 

  58. D. E. Schafer, F. Wudl, G. A. Thomas, J. P. Ferraris, and D. O. Cowan, Sol. St. Comm., 14, 347 (1974).

    Google Scholar 

  59. M. B. Salamon, J. W. Bray, G. DePasquali, R. A. Craven, R. Herman, G. Stucky, and A. Schultz, Phys. Rev., Bll, 619 (1975).

    Google Scholar 

  60. J. Bardeen, Sol. St. Comm., 13, 357 (1973).

    Google Scholar 

  61. M. J. Cohen, L. B. Coleman, A. F. Garito, and A. J. Heeger, Phys. Rev., B10, 1298 (1974).

    Google Scholar 

  62. R. V. Gemmer, D. O. Cowan, A. N. Bloch, R. E. Pyle, and R. Banks, Mol. Cryst. and Liq. Cryst., 32, 227 (1976).

    Google Scholar 

  63. A. N. Bloch, J. P. Ferraris, D. O. Cowan, and T. O. Poehler, Sol. St. Comm., 13, 753 (1973).

    Google Scholar 

  64. L. J. Buravov and I. F. Schegolev, Prib. Tek. Eksp., 2, 171 (1971).

    Google Scholar 

  65. M. Cohen, S. K. Khanna, W. J. Gunning, A. F. Garito, and A. J. Heeger, Sol. St. Comm., 17, 367 (1975).

    Google Scholar 

  66. A. M. Clogston, Bell System Tech. J., 30, 491 (1951).

    Google Scholar 

  67. A. Madhukar and M. H. Cohen, preprint; A. A. Gogolin, V. I. Mel'nikov, and E. I. Rashba, this volume.

    Google Scholar 

  68. J. B. Torrance, E. E. Simonyi, and A. N. Bloch, Bull. Amer. Phys. Soc., 20, 497 (1975), and to be published.

    Google Scholar 

  69. See, for example, P. E. Seiden and D. Cabib, Phys. Rev., B13, 1846 (1976).

    Google Scholar 

  70. R. A. Craven, M. B. Salamon, G. DePasquali, R. M. Herman, G. Stucky, and A. Schultz, Phys. Rev. Lett., 32, 769 (1974).

    Google Scholar 

  71. R. V. Gemmer, D. O. Cowan, T. O. Poehler, A. N. Bloch, and R. H. Banks, J. Org. Chem., 40, 3544 (1975).

    Google Scholar 

  72. H. Fukuyama, T. M. Rice, and C. M. Varma, Phys. Rev. Lett., 33, 305 (1974).

    Google Scholar 

  73. A. Luther and V. J. Emery, Phys. Rev. Lett., 33, 589 (1974).

    Google Scholar 

  74. T. Carruthers, A. N. Bloch, and D. O. Cowan, Bull. Amer. Phys. Soc., 21, 313 (1976), and to be published.

    Google Scholar 

  75. P. M. Horn and D. Rimai, Phys. Rev. Lett., 36, 809 (1976); and P. M. Horn and D. Guidotti, preprint.

    Google Scholar 

  76. P. Bak and V. J. Emery, Phys. Rev. Lett., 36, 978 (1976).

    Google Scholar 

  77. The 47 K anomaly in the conductivity, though absent in the data of Ref. 13c, has now been observed independently in several laboratories. To our knowledge it was first reported by us (Ref. 72), and separately by P. Horn and D. Guidotti, at the 1976 March meeting of the American Physical Society (Atlanta, Ga.).

    Google Scholar 

  78. See, for example, Aldert van der Ziel, Noise: Sources, Characterization, Measurement (Prentice-Hall, Englewood Cliffs, N. J., 1970).

    Google Scholar 

  79. V. K. S. Shante, A. N. Bloch, T. Carruthers, and D. O. Cowan, Bull. Amer. Phys. Soc., 21, 313 (1976), and to be published.

    Google Scholar 

  80. K. Bechgaard and B. S. Jensen, this volume.

    Google Scholar 

  81. P. Horn, private communication.

    Google Scholar 

  82. J. E. Gulley and J. F. Weiler, Phys. Rev. Lett., 34, 1061 (1975).

    Google Scholar 

  83. Y. Tomkiewicz, A. R. Taranko, and J. B. Torrance, Phys. Rev. Lett., 36, 751 (1976).

    Google Scholar 

  84. T. O. Poehler, R. M. Somers, A. N. Bloch, and D. O. Cowan, preprint.

    Google Scholar 

  85. H. Kahlert, Sol. St. Comm., 17, 1161 (1975); K. Seeger, Sol. St. Comm., 19, 245 (1976).

    Google Scholar 

  86. M. J. Cohen, P. R. Newman, and A. J. Heeger, preprint.

    Google Scholar 

  87. See, for example, K. Seeger, Semiconductor Physics (Springer-Verlag, New York, 1973).

    Google Scholar 

  88. H. A. Mook and C. R. Watson, preprint.

    Google Scholar 

  89. M. J. Rice, A. R. Bishop, J. A. Krumhansl, and S. E. Trullinger, Phys. Rev. Lett., 36, 432 (1976).

    Google Scholar 

  90. D. B. Tanner, C. S. Jacobsen, A. F. Garito, and A. J. Heeger, Phys. Rev. Lett., 32, 1301 (1974); 33, 1559 (1974); Phys. Rev., B13, 3381 (1976).

    Google Scholar 

  91. U. Fano, Phys. Rev., 124, 1886 (1961).

    Google Scholar 

  92. This effect is distinct from the stabilization of the Peierls gap by the softening of intramolecular optical modes suggested by M. J. Rice, C. B. Duke, and N. O. Lipari [Sol. St. Comm., 17, 1089 (1975)].In fact, their calculation is flawed in its assumption that the phases of the intramolecular and intermolecular soft modes are arbitrary. The correct theory [A. Madhukar, Chem. Phys. Lett., 27, 606 (1974)] recognizes that the former modes build up charge around the lattice sites and the latter in the bonding regions; hence the two instabilities compete.

    Google Scholar 

  93. H. Hinkelmann and H. G. Reik, Sol. St. Comm., 16, 567 (1975).

    Google Scholar 

  94. J. J. Ritsko, D. J. Sandman, A. J. Epstein, P. C. Gibbons, S. E. Schnatterly, and J. Fields, Phys. Rev. Lett., 34, 1330 (1975).

    Google Scholar 

  95. P. F. Williams and A. N. Bloch, Phys. Rev. Lett., 36, 64 (1976).

    Google Scholar 

  96. G. Giulliani, E. Tosatti, and M. P. Tosi, Lett. Nuovo Cimento, 16, 385 (1976).

    Google Scholar 

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L. Pál G. Grüner A. Jánossy J. Sólyom

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Bloch, A.N. (1977). Chemical trends in organic conductors: Stabilization of the nearly one-dimensional metallic state. In: Pál, L., Grüner, G., Jánossy, A., Sólyom, J. (eds) Organic Conductors and Semiconductors. Lecture Notes in Physics, vol 65. Springer, Berlin, Heidelberg. https://doi.org/10.1007/BFb0012387

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