Skip to main content
Log in

Role of sodium silicate in phosphate flotation

  • Published:
Mining, Metallurgy & Exploration Aims and scope Submit manuscript

Abstract

The role of sodium silicate in the anionic flotation of a Floridaphosphate ore was investigated using laboratory continuous flotation tests, frothability tests and SEM observations.

In the absence of sodium silicate, Ca++ promoted the unwanted activation of quartz by forming calcium bearing precipitates.

The addition of sodium silicate enhanced the flotation efficiency through:

  1. 1)

    the removal of impurity minerals and calcium-bearing precipitates from quartz surfaces by dispersion,

  2. 2)

    drier and more persistent froths stabilized by oily droplets containing calcium silicate precipitates, and

  3. 3)

    higher specific flotation rates of phosphate relative to quartz, leading to faster flotation rates and increased selectivity of separation.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  • Anon., 1966, “Silicate P’s & Q’s”, Philadelphia Quartz Co. Bulletin, Vol. 46, No. 4, 2 p.

  • Aveston, J., 1965, “Hydrolysis of Sodium Silicate: Ultracentrifugation in Chloride Solutions.” Journal of the Chemical Society, pp. 4444–4448.

  • Borisov, M.V. and Ryzhenko, B.N., 1974, “Investigation of Infrared Spectra of Aqueous Sodium Silicate Solutions,” Geochemistry International, Vol. 11 (2), pp. 951–959.

    Google Scholar 

  • Debye, P. and Nauman, R.V., 1961, “A Light Scattering Study of the Aggregation of Acidified Sodium Silicate Solutions,” Journal of Physical Chemistry, Vol. 65, pp. 10–12.

    Article  Google Scholar 

  • Dho, H., 1988, M.S. Thesis, University of Minnesota.

  • Falcone, Jr., J.S., 1981, “Recent Advances in the Chemistry of Sodium Silicates: Implications for Ore Beneficiation,” SME/AIME Fall Meeting, Denver, SME preprint No. 81-315.

  • Krishnan, S.V. and Iwasaki, I., 1982, “Sodium Silicate as a Dispersant in the Selective Flocculation of Iron Ores,” Transactions, SME-AIME, Vol. 272, pp. 1984–1988.

    Google Scholar 

  • Lawver, J.E., Raulerson, J.D., and Cook, C.C., 1981, “New Techniques in Beneficiation of Phosphate Rocks,” Transactions, SME/AIME, Vol. 268, pp. 1787–1802.

    Google Scholar 

  • Lentz, C.W., 1964, “Silicate Minerals as Sources of Trimethylsilyl Silicates and Silicate Structure Analysis of Sodium Silicate Solutions,” Inorganic Chemistry, Vol. 3 (1), pp. 574–579.

    Article  Google Scholar 

  • Lovell, V.M., 1976, “Froth Characteristics in Phosphate Flotation,” Flotation, Gaudin Memorial Volume, (Fuerstenau, M.C., ed.), AIME, New York, Vol. 1, pp. 596–621.

    Google Scholar 

  • Luttrell, G.H., and Yoon, R.H., 1983, “Automation of a Laboratory Flotation Machine for Improved Performance,” International Journal of Mineral Processing, Vol. 10, pp. 165–172.

    Article  Google Scholar 

  • Mishra, S.K., 1982, “Electrokinetic Properties and Flotation Behavior of Apatite and Calcite in the Presence of Sodium Oleate and Sodium Metasilicate,” International Journal of Mineral Processing, Vol. 9, pp. 59–73.

    Article  Google Scholar 

  • O’Conner, R.L., 1961, “The Reaction Rates of Polysilicic Acids with Molybdic Acids,” Journal of Physical Chemistry, Vol. 65, pp. 1–5.

    Article  Google Scholar 

  • Schuhmann, R., Jr., 1942, “Flotation Kinetics I,” Journal of Physical Chemistry, Vol. 46, pp. 891–902.

    Article  Google Scholar 

  • Sun, S.C., Snow, R.E., and Purcell V.I., 1957, “Flotation Characteristics of a Florida Leached Zone Phosphate Ore with Fatty Acids,” Transactions, AIME, Vol. 208, pp. 70–75.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

SME preprint 90-130, SME Annual Meeting, Salt Lake City, UT, Feb. 26–March 1, 1990.

Discussion of this paper must be submitted, in duplicate, prior to March 1, 1991.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Dho, H., Iwasaki, I. Role of sodium silicate in phosphate flotation. Mining, Metallurgy & Exploration 7, 215–221 (1990). https://doi.org/10.1007/BF03402921

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF03402921

Navigation