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A new crystal engineering approach for the synthesis of {[K.18-Crown-6]I3}n as a nanotube-Like and recyclable catalyst for the chemoselective silylation of alcohols

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Abstract

Reaction of 18-crown-6 with KI in ethanol solution followed by addition of iodine (I2) afforded a unique triiodide salt with a nanotube-like structure ({[K.18-Crown-6]I3}n). It is shown that this reagent may be used for the chemoselective trimethylsilylation of alcohols. The synthesis of the crystalline reagent is a good example of crystal engineering. Reagent was recycled and reused.

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Authors and Affiliations

  1. Faculty of Chemistry, Bu-Ali Sina University, P. O. Box 4135, Hamedan, 6517838683, Iran

    M. A. Zolfigol, E. Kolvari, N. Koukabi & S. Salehzadeh

  2. Schoolof Pharmacy, Hamedan University of Medical Sciences, Hamedan, Iran

    G. Chehardoli

  3. Department of Chemistry, University of Sheffield, Sheffield, S3 7HF, UK

    I. S. Tidmarsh

  4. Department of Chemistry, Faculty of Sciences, Persian Gulf University, Bushehr, 75169, Iran

    K. Niknam

Authors
  1. M. A. Zolfigol
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  2. E. Kolvari
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  3. N. Koukabi
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  4. S. Salehzadeh
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  5. G. Chehardoli
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  6. I. S. Tidmarsh
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  7. K. Niknam
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Correspondence to M. A. Zolfigol.

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Zolfigol, M.A., Kolvari, E., Koukabi, N. et al. A new crystal engineering approach for the synthesis of {[K.18-Crown-6]I3}n as a nanotube-Like and recyclable catalyst for the chemoselective silylation of alcohols. JICS 8, 484–494 (2011). https://doi.org/10.1007/BF03249082

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