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Selectfluor™ promoted synthesis of 9-aryl-1,8-dioxooctahydroxanthane derivatives under solvent-free conditions

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Abstract

A novel and efficient procedure for the synthesis of 1,8-dioxo-octahydro-xanthenes through one-pot condensation of 5,5- dimethyl-1,3-cyclohexadione with aryl aldehydes in the presence of selectfluor™ [1-(chloromethyl)-4-fluoro-1,4- diazoniabicyclo[2,2,2]octane bis(tetrafluoroborate) as catalyst under solvent free conditions was applied. It demonstrated several advantages such as good yields of products, simple operation, convenient separation, and inexpensive catalyst.

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Authors and Affiliations

  1. Department of Chemistry, Payame Noor University (PNU), P. O. Box 97, Abhar, Islamic Republic of Iran

    M. R. Poor Heravi

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  1. M. R. Poor Heravi
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Correspondence to M. R. Poor Heravi.

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Poor Heravi, M.R. Selectfluor™ promoted synthesis of 9-aryl-1,8-dioxooctahydroxanthane derivatives under solvent-free conditions. JICS 6, 483–488 (2009). https://doi.org/10.1007/BF03246525

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  • DOI: https://doi.org/10.1007/BF03246525

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