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Thermodynamic investigation of the molecular interactions of 4-nitrophenol with free-bases meso-tetraarylporphyrins

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Abstract

The molecular interactions of 4-Nitrophenol (4NP) with free-base meso-tetraarylporphyrins (H2T(4-X)PP; X = OCH3, CH3, H, Cl) have been studied. The formation constants and other thermodynamic parameters were calculated by using UV-Vis spectrophotometry titration results. The formation constants show the following trend relative to X substituent of porphyrins: H2T(4-CH3O)PP > H2T(4-CH3)PP > H2TPP > H2T(4-Cl)PP.

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Authors and Affiliations

  1. Chemistry Department, College of Sciences, Lorestan University, Khoramabad, I.R. Iran

    A. Zabardasti & Z. Rezvani-Abkenari

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  1. A. Zabardasti
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  2. Z. Rezvani-Abkenari
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Correspondence to A. Zabardasti.

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Zabardasti, A., Rezvani-Abkenari, Z. Thermodynamic investigation of the molecular interactions of 4-nitrophenol with free-bases meso-tetraarylporphyrins. JICS 5, 57–61 (2008). https://doi.org/10.1007/BF03245815

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  • DOI: https://doi.org/10.1007/BF03245815

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