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Simultaneous electrochemical and electron paramagnetic resonance studies of fullerene anion radicals C 1−60 and C 3−60

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Abstract

Simultaneous electrochemical and electron paramagnetic resonance experiments have been carried out on the reduced C60 fullerene to examine theg-factor assignment of the radical species. C 1−60 and C 3−60 show the following EPR characteristics at room temperature: C 1−60 :g 1−=2.0002±0.0001, 2ΔB 1s=0.17 mT, and C 3−60 :g 3−=2.0008±0.0002, 2ΔB 1s=0.07 mT. EPR linewidths are apparently narrower compared to those in most of the spectra previously reported. Variable temperature EPR study on solution containing C 1−60 has shown thatg 1− value is not while the linewidth is only slightly temperature dependent.

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Authors and Affiliations

  1. Institute of Molecular Physics, Polish Academy of Sciences, Poznan, Poland

    L. Piekara-Sady, J. Stankowski, W. Kempinski & Z. Trybula

  2. Institute of Organic and Physical Chemistry, Russian Academy of Sciences, Arbusov str. 8, 420083, Kazan, Russian Federation

    A. V. Il’yasov & V. Morozov

Authors
  1. L. Piekara-Sady
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  2. A. V. Il’yasov
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  3. V. Morozov
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  4. J. Stankowski
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  5. W. Kempinski
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  6. Z. Trybula
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Piekara-Sady, L., Il’yasov, A.V., Morozov, V. et al. Simultaneous electrochemical and electron paramagnetic resonance studies of fullerene anion radicals C 1−60 and C 3−60 . Appl. Magn. Reson. 9, 367–372 (1995). https://doi.org/10.1007/BF03161959

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  • DOI: https://doi.org/10.1007/BF03161959

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