Abstract
A CIDEP study of the radical adducts formed by addition of phosphonyl radicals to several unsaturated organic compounds is described. The complicated time-resolved ESR spectra obtained for these adducts were interpreted on the basis of competing chemical and physical processes involved in polarization transfer to the secondary radicals produced. This is a novel example illustrating for the first time radical pair polarization transfer in solution.
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Akiyama, K., Depew, M.C. & Wan, J.K.S. Spin polarization transfer during the addition reaction of phosphorus radicals to simple olefins in solution. Res Chem Intermed 11, 25–36 (1989). https://doi.org/10.1007/BF03051816
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DOI: https://doi.org/10.1007/BF03051816