Abstract
A linear logarithmic dependence of the standard rate constant on the apparent free energy of activation for the electrode process has been observed for the reduction of zinc in the presence of alanine, glycine, aspartic acid, glutamic acid, ammonia, ethylenediamine and tartrate. The value of the slope is close to the transfer coefficient of zinc in these media. For a homogeneous electron-exchange reaction, such as the disproportionation of uranium(V) in solution, a linear free energy relation has been observed.
Similar content being viewed by others
References
Chauhan B G, Fawcett W R and McCarrick T A 1975J. Electroanal. Chem. 58 275
Imai H 1959J. Electrochem. Soc. Japan 27 55
Marcus R A 1965J. Chem. Phys. 43 679
Marcus R A 1968Electrochim. Acta 13 995
Martell A E and Calvin M 1956Chemistry of the Metal Chelate Compounds (N J: Prentice-Hall Inc.) p. 181
Matsuda M and Ayabe Y 1959Z. Elektrochem. 63 1164
Matsuda M and Ayabe Y 1962Z. Elektrochem. 66 469
Mehta M M, Saraiya S C and Sundaram A K 1966Proc. Indian Acad. Sci. A63 371
Sundaram A K 1961 Ph.D. Thesis (University of Bombay)
Sundaram R 1969 M.Sc. Thesis (University of Bombay)
Sundaresan R, Saraiya S C and Sundaram A K 1967aProc. Indian Acad. Sci. A66 184
Sundaresan R, Saraiya S C and Sundaram A K 1967 bProc. Indian Acad. Sci. A66 120
Sundaresan R, Saraiya S C, Radhakrishnan T P and Sundaram A K 1968Electrochim. Acta 13 443
Vlcek A A 1958Disc. Faraday Soc. 26 164
Vlcek A A 1959Coll. Czech. Chem. Communs. 24 3538
Vlcek A A 1962 inProgress in Polarography eds P Zuman & I M Kolthoff Vol. I, (New York: Interscience Pub.) p. 269.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Radhakrishnan, T.P., Sundaram, A.K. Free energy relationship in some electron-transfer reactions. Proc. Indian Acad. Sci. 86, 53–57 (1977). https://doi.org/10.1007/BF03046652
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF03046652