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Preoxidation and hydrogen reduction of ilmenite in a fiuidized bed reactor

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Abstract

Studies on preoxidation and hydrogen reduction of Quilon-grade ilmenite have been carried out in a fluidized bed reactor. During preoxidation, the effect of various parameters such as temperature, gas flow rate, and period of reaction has been studied. Hydrogen reduction studies have been carried out both for raw and preoxidized ilmenite. Results obtained on the conversion rate of iron oxide to metallic iron for the preoxidation as well as the reduction period showed three distinct stages: (1) initial slow induction stage; (2) intermediate acceleratory stage; and (3) final slowing down process. Kinetic data plot on -In (1 -x) vs time for metallization of iron oxide showed a linear trend for preoxidation and hydrogen reduction.

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References

  1. C. Palmer:Am. J. Sci., 1909. vol. 28, pp. 65–75.

    Google Scholar 

  2. A.K. Temple:Economic Geology, 1966. vol. 61, pp. 695–714.

    CAS  Google Scholar 

  3. I.E. Grey and A.F. Reid:Am. Mineral., 1975. vol. 60, pp. 898–906.

    CAS  Google Scholar 

  4. S.K. Gupta, V. Rajakumar, and P. Grieveson:Metall. Trans. B, 1991, vol. 22B, pp. 711–16.

    Article  CAS  Google Scholar 

  5. J.J. Henn and J.A. Barclay: Information Circular, United States Bureau of Mines No. 8450. 1970, pp. 1–27.

  6. F.R. Hartley:8th Commonwealth Mining and Metallurgy Congr., Australia-New Zealand, 1965;Proc. General J.T. Woodcock, R.T. Madigan, and R.G. Thomas, eds., Australasian Institute of Mining and Metallurgy, 1967, pp. 1373–86.

  7. A.D. Brent and K.J. Reid: InPlasma Processing and Synthesis of Materials, D. Apelian and J. Szekely, eds., Materials Research Society, Pittsburgh, PA, 1987. pp. 399–404.

    Google Scholar 

  8. L.E. Lynd: USBM Mineral Commodity Profile, (Titanium) 1983.

  9. W.W. Minkler and E.F. Baroch:Met. Treat., 1981, pp. 171–82.

  10. S. Fukushima and Y. Sugawara: inLight Metals, H. Forberg, ed., AIME, New York, NY, 1974, pp. 443–66.

    Google Scholar 

  11. A. Fuwa, E. Kimura, and S. Fukushima:Metall. Trans. B, 1978, vol. 9B, pp. 643–52.

    CAS  Google Scholar 

  12. R.B. Smith, A. Tetlon, and C.L. Thompson:Pyrometallurgy—87, Institution of Mining and Metallurgy, London, 1987, pp. 907–35.

    Google Scholar 

  13. S.K. Gupta, V. Rajakumar, and P. Grieveson:Can. Metall. Q., 1990, vol. 29, pp. 43–49.

    CAS  Google Scholar 

  14. D.B. Rao and M. Rigaud:High Temp. Sci., 1974, vol. 6, pp. 323–41.

    CAS  Google Scholar 

  15. V.B. Festisov, L.I. Leont’yev, B.Z. Kudinov, and S.V. Ivanova:Izv. Akad. Navk SSSR Metall., 1968, vol. 2, pp. 47–49; English translation:Russ. Metall. (Metally), 1968, vol. 2, pp. 35–37.

    Google Scholar 

  16. R.G. Becher, R.G. Cannina, B.A. Goodheart, and S. Uusna:Aust. Inst. Min. Met., 1965, Proc. No. 214, pp. 21–44.

  17. P. Ramdohr:Abhandl. Preuss. Akad. Weiss. Jahvg. Math-Nat. Klasse, 1939, vol. 14, pp. 12–14;Chem. Abstr., 1941, vol. 35, pp. 12–14.

    Google Scholar 

  18. J.L. Overholt, G. Vaux, and J. L. Rodda:Am. Mineral., 1950, vol. 35, pp. 117–19.

    CAS  Google Scholar 

  19. C.E. Curnov and L.G. Parry:Nature (London), 1954, vol. 174, p. 1101.

    Article  Google Scholar 

  20. M.D. Karkhanavala and A.C. Momin:Economic Geology, 1959, vol. 54, pp. 1095–1102.

    Article  CAS  Google Scholar 

  21. K. Borowiec and T. Rosenquist:Scand. J. Metall., 1981, vol. 10, pp. 217–24.

    CAS  Google Scholar 

  22. G. Teufer and A.K. Temple:Nature (London), 1966 vol. 211, pp. 179–81.

    Article  CAS  Google Scholar 

  23. I.E. Grey and A.F. Reid:J. Solid State Chem., 1972, vol. 4, pp. 186–94.

    Article  CAS  Google Scholar 

  24. S.K. Gupta, V. Rajakumar, and P. Grievson:Metall. Trans. B, 1989, vol. 20B, pp. 735–45.

    Article  CAS  Google Scholar 

  25. D.G. Jones:Trans. Inst. Min. Met., 1976, Sec. C, vol. 82, pp. 186–92.

    Google Scholar 

  26. B.F. Bracanin, P.W. Cassidy, J.M. Mackay, and H.W. Hockin: TMS Paper No. A72-31, TMS, Warrendale, PA, 1972, pp. 209–59.

    Google Scholar 

  27. D. Sathiyamoorthy and P.L. Vijay: Presented paper (unpublished) at the 41st Annual Technical Meeting of IIM, Trivandrum, India, Nov. 12–14, 1987.

  28. G.V. Shamakov, L.I. Leontev, V.B. Fetisov, and B.Z. Kudinov: (USSR)Izv. Akad., Nauk SSSR, Metall., 1968, vol. 6. pp. 60–62.

    Google Scholar 

  29. R.N. Walsh, H.W. Hockin, D.R. Brandt, P.L. Dietz, and P.R. Girardot:Trans. TMS-AIME, 1960, vol. 218, pp. 994–1003.

    CAS  Google Scholar 

  30. N.C. Kothari:Int. J. Min. Proc., 1974, vol. 1, pp. 287–305.

    Article  CAS  Google Scholar 

  31. M. Onoda, M. Othai, and K. Sanbogi:Tohekv Daigaku Senko Sciren Kenkyusho Iho., 1965, vol. 21, p. 159.

    CAS  Google Scholar 

  32. A. Yamaguchi and J. Moriyama:Men. Fac. Eng. Kyoto Univ., 1966, vol. 28, pp. 389–403.

    CAS  Google Scholar 

  33. R.P. Donnelly, L.J. Brennan, W. McMullan, and A. Rouillard:Aust. Min., 1970, vol. 62, pp. 58–65.

    Google Scholar 

  34. N.F. Vanderbrack:J. Less-Common Met., 1961, vol. 3, pp. 293–304.

    Article  Google Scholar 

  35. V.G. Neurgaonkar, R.W. Shinde, J. Pries, and A.N. Gokaran: inRecent Trends in Chemical Reaction Engineering, B.D. Kulkarni, R.A. Mashalkar, and M.M.S. Sharma, eds., Wiley Eastern Ltd., New Delhi, 1987, vol. 11, pp. 282–88.

    Google Scholar 

  36. Thomas S. Mackey:J. Met., 1994, vol. 46 (4), pp. 59–64.

    Google Scholar 

  37. S.Z.El. Tawil, I.M. Morsi, and A.A. Francis:Can. Met. Q., 1993, vol. 32, pp. 281–88.

    Google Scholar 

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Vijay, P.L., Venugopalan, R. & Sathiyamoorthy, D. Preoxidation and hydrogen reduction of ilmenite in a fiuidized bed reactor. Metall Mater Trans B 27, 731–738 (1996). https://doi.org/10.1007/BF02915601

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