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The height of the barrier hindering rotation in nitrosodimethylamine

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Il Nuovo Cimento (1955-1965)

Summary

The height of the barrier hindering rotation in nitroso-dimethylamine has ben calculated by a simpe molecular orbital treatment, in itsn electrons approximation. Σ bond energies and non bonding-forces are also evaluated. Fair agreement with experimental results is obtained.

Riassunto

é stata calcolata l’altezza della barriera di rotazione interna della nitrosodimetilammina con una trattazione semplificata della teoria degli orbitali molecolari nell’approssimazione π. Abbiamo anche calcolato Je energie dei legami Σ e quelle relative alle forze di non legame. I risultati ottenuti risultano in buon accordo con quelli sperimentali.

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Authors and Affiliations

  1. Department of Physical Chemistry, University of Milan, Italy

    M. Simonetta & S. Carrà

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  1. M. Simonetta
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  2. S. Carrà
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Simonetta, M., Carrà, S. The height of the barrier hindering rotation in nitrosodimethylamine. Nuovo Cim 9, 902–907 (1958). https://doi.org/10.1007/BF02903131

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  • DOI: https://doi.org/10.1007/BF02903131

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