Abstract
Blends of poly(l-lactide) (PLA) and low density polyethylene (LDPE) were prepared by melt mixing in order to improve the brittleness of PLA. A reactive compatibilizer with glycidyl methacrylate (GMA), PE-GMA, was required as a compatibilizer due to the immiscibility between PLA and LDPE. It contributes to reduce the domain size of dispersed phase and enhance the tensile properties of PLA/LDPE blends, especially for PLA matrix blends. A reaction product between PLA and PE-GMA, which was formed during melt-mixing and considered to act as a reactive compatibilizer, was characterized using1H-NMR spectroscopy.
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K. Sudesh, H. Abe, and Y. Doi,Prog. Polym. Sci.,25, 1503 (2000).
Y. Ikada and H. Tsuji,Macromol. Rapid. Comm.,21, 117 (2000).
R. E. Drumright, P. R. Gruber, and D. E. Henton,Adv. Mater.,12, 1841 (2000).
D. R. Paul and C. B. Bucknall (Eds.), “Polymer Blends”, John & Wiley and Sons, New York, 2000.
S. Krause and S. H. Goh in “Polymer Handbook, 4th Ed.”, (J. Brandrup, E. H. Immergut, and E. A. Grulke Eds.), VI/409, John & Wiley and Sons, New York, 1999.
S. Datta and D. J. Lohse, “Polymeric Compatibilizers”, Hanser, Munich, 1996.
U. Sundararaj and C. W. Macosko,Macromolecules,28, 2647 (1995).
D. J. Lohse,Polym. Eng. Sci.,26, 1500 (1986).
Q. T. Pham, R. Petiaud, H. Waton, and M-F. L- Darricades, “Proton and Carbon NMR Spectra of Polymers”, CRC Press, Boca Raton, 1991.
C. T. Maa and F. C. Chang,J. Appl. Polym. Sci.,49, 913 (1993).
D. Y. Chang and F. C. Chang,Polym. Networks Blends,4, 157 (1994).
N. C. Liu and W. E. Baker,Adv. Polym. Technol.,11, 249 (1992).
D. Godshall, C. White, and G. L. Wilkes,J. Appl. Polym. Sci.,80, 130 (2001).
A. Margolina and S. Wu,Polymer,29, 2170 (1988).
S. Wu,Polym. Eng. Sci.,27, 335 (1987).
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Kim, Y.F., Choi, C.N., Kim, Y.D. et al. Compatibilization of immiscible poly(l-lactide) and low density polyethylene blends. Fibers Polym 5, 270–274 (2004). https://doi.org/10.1007/BF02875524
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DOI: https://doi.org/10.1007/BF02875524