Abstract
The solid electrolytes, BaCe0.8Ln0.2O2.9(Ln: Gd, Sm, Eu), were prepared by the sol-gel method. XRD indicated that a pure orthorhombic phase was formed at 900°C. The synthesis temperature by the sol-gel method was about 600°C lower than the high temperature solid phase reaction method. The electrical conductivity and impedance spectra were measured and the conduction mechanism was studied. The grain-boundary resistance of the solid electrolyte could be reduced or eliminated by the sol-gel method. The conductivity of BaCe0.8Gd0.2O2.9 is 7.87 × 10-2 S· cm-1 at 800°C. The open-rireuit voltage of hydrogen-oxygen fuel cell using BaCe0.8Gd0.2O2.9 as electrolyte was near to 1 V and its maximum power density was 30 mW· cm-2.
Similar content being viewed by others
References
Minh, N. Q., Ceramic fuel cells,J. Am. Ceram. Soc., 1993, 76(3): 563.
Jiang, Y., Li, W. Z., Wang, S. Z., Progress in high temperature solid oxide fuel cell (SOFC),Progress in Chemistry (in Chinese), 1997, 9(4): 387.
Meng, G. Y., Liu, W. Y., Peng, D. K., New solid state fuel cells—green power source for the 21st century, in 97th Xiangshan Sci. Conf. on New SSFCS (Beijing) (ed. Meng Guangyao), Hefei: University of Science and Technology of China, 1998, 1–16.
Shuk, P., Wiemhofer, H. -D., Guth, U. et al., Oxide ion conducting solid electrolytes based on Bi2O3,Solid State Ionics, 1996, 89: 179.
Inaba, H., Tagawa, H., Ceria-based solid electrolytes,Solid State Ionics, 1996, 83: 1.
Iwahara, H., Technological challenges in the application of proton conducting ceramics,Solid State Ionics, 1995, 77: 289.
Bonanos, N., Knight, K. S., Ellis, B., Perovskite solid electrolytes: structure, transport properties and fuel cell applications,Solid State Ionics, 1995, 79: 161.
Iwahara, H., Proton conducting ceramics and their applications,Solid State Ionics, 1996, 86-88: 9.
Iwahara, H., Uchida, K., Ono, K. et al., Proton conduction in sintered oxides based on BaCeO3,J. Electrochem. Soc., 1988, 135(2): 529.
Frade, J. R., Theoretical behavior of concentration cells on ABO3 perovskite materials with proton and oxygen ion conduction,Solid State Ionics, 1995, 78: 87.
Huang, K., Feng, M., Goodenough, J. B., Sol-gel synthesis of a new oxide-ion conductor Sr- and Mg-doped LaGaO3 perovskiteJ. Am. Ceram. Soc, 1996, 79(4): 1100.
Author information
Authors and Affiliations
Additional information
Project supported by the State Key Program for Basic Research and the National Natural Science Foundation of China (Grant No. 29741002).
Rights and permissions
About this article
Cite this article
Jiang, K., He, Z., Meng, J. et al. Low temperature preparation and fuel cell properties of rare earth doped barium cerate solid electrolytes. Sc. China Ser. B-Chem. 42, 298–304 (1999). https://doi.org/10.1007/BF02874246
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF02874246