Abstract
Two new ternary oxidic compositions of CuNiSnO4 have been prepared. The ternary composition Cu2+Ni2+SnO4 in orthorhombic symmetry with lattice dimensionsa 0=5·773 ± 0·01 Å;b 0=8·377 ± 0·01 Å;c 0=10·094 ± 0·01 Å, while Cu+Ni3+SnO4 is also orthorhombic but with lattice dimensionsa 0=5·737 ± 0·01 Å;b 0=7·125 ± 0·01 Å andc 0=10·071 ± 0·01 Å. The variation of electrical conductance with temperature indicates the semiconducting nature of these compositions. Hot-probe method indicatesp-type semiconduction in both the compositions
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Sampath, S., Tare, M.P., Tripathi, R.R. et al. X-ray crystallographic and conductance study of CuNiSnO4 synthesized by two different methods. Bull. Mater. Sci. 17, 487–492 (1994). https://doi.org/10.1007/BF02757893
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DOI: https://doi.org/10.1007/BF02757893