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Structure control, coating properties, and durability of fluorinated acrylic-based polymers

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Journal of Coatings Technology

Abstract

Fluorinated acrylates were employed for the synthesis of conventional, side-chain fluorinated, fully acrylic random copolymers, and of more unusual hybrid copolymers with vinyl ethers. The latter can feature alternating structure and peculiar material properties associated with fluorine or fluorinated groups substitution onto the polymer backbone. Improved efficacy and durability of the resulting coating, highly desirable for the consolidation and protection of highly valued works of art, was achieved through a systematic approach involving a detailed study of their photodegradation behavior, and extensive testing of protection efficacy upon application onto micro-and macroporous stone substrates of different chemical composition and morphology.

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Authors and Affiliations

  1. University of Pisa, Italy

    Valter Castelvetro, Mauro Aglietto & Francesco Ciardelli

  2. University of Torino, Italy

    Oscar Chiantore & Massimo Lazzari

  3. Centro C.N.R. “Gino Bozza”, Italy

    Lucia Toniolo

Authors
  1. Valter Castelvetro
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  2. Mauro Aglietto
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  3. Francesco Ciardelli
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  4. Oscar Chiantore
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  5. Massimo Lazzari
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  6. Lucia Toniolo
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Corresponding author

Correspondence to Francesco Ciardelli.

Additional information

Dipartimento di Chimica e Chimica Industriale, Via Risorgimento 35, 56126 Pisa, Italy.

Dipartimento di Chimica IFM, via Pietro Giuria 7, 10125 Torino, Italy.

Piazza Leonardo da Vinci 32, 20133 Milano, Italy, Lucia.

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Castelvetro, V., Aglietto, M., Ciardelli, F. et al. Structure control, coating properties, and durability of fluorinated acrylic-based polymers. Journal of Coatings Technology 74, 57–66 (2002). https://doi.org/10.1007/BF02697984

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