Skip to main content
SpringerLink
Log in

Effect of nickel additions on the oxidation kinetics of double titanium and chromium carbide powder

  • Physicochemical And Structural Investigations Of Materials
  • Published:
Powder Metallurgy and Metal Ceramics Aims and scope

Abstract

The effect of powdered nickel additions (10–33 mass %) on the oxidation kinetics of double titanium-chromium carbide produced by the method of self-propagating high-temperature synthesis, and also that of plating the synthesized carbide powder with nickel (26 mass %) was studied. The effect of nickel concentration and powder particle size on the oxidation resistance at different temperatures was different. However, it can be stated that plating the carbide powder with nickel increased its oxidation resistance at all temperatures in the range 600–1000°C, excepting 700°C. The degree of oxidation of the carbide and nickel constituents were estimated. Activation energies for the initial and parabolic stages of oxidation were determined.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. V. M. Shkiro and I. P. Borovinskaya, “Study of the laws of combustion of mixtures of titanium with carbon,” in:Combustion Processes in Chemical Technology and Metallurgy [in Russian]. Chernogolovka (1975), pp. 252–258.

  2. I. N. Gorbatov, N. S. Il’chenko, A. V. Terent’ev, et al., “Effect of plating binary titanium-chromium carbide on the properties of plasma coatings,”Fiz. Khim. Obrab. Mater., No. 3, 69–73 (1991).

    Google Scholar 

  3. G. N. Komratov, I. D. Chausskaya, L. V. Kustova, et al., “Oxidation kinetics of double titanium-chromium carbide powders of various compositions at 600 C,”Preprint, Academy of Sciences, SSSR, Chernogolovka (1990).

  4. I. N. Gorbatov, V. M. Shkiro, R. E. Terent’ev, et al., “Study of the properties of gas-thermal coatings of composite nickel-titanium and chromium carbide powder,”Fiz. Khim. Obrab. Mater., No. 4, 102–106 (1991).

    Google Scholar 

  5. O. Kubashevskii and B. Hopkins,Oxidation of Metals and Alloys [Russian translation]. Metallurgiya, Moscow (1965).

    Google Scholar 

  6. É. A. Pugach, G. G. Postalova, Ya. V. Ivas’kevich, et al., “Effect of nickel on the oxidation of TiCrB2,”Sverkhtverd. Mater., No. 1, 17–20 (1985).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Structural Kinetics, Russian Academy of Sciences, Chernogolovka

    G. N. Komratov

Authors
  1. G. N. Komratov
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Poroshkovaya Metallurgiya. Nos. 1/2(411), pp. 76–82, January–February, 2000.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Komratov, G.N. Effect of nickel additions on the oxidation kinetics of double titanium and chromium carbide powder. Powder Metall Met Ceram 39, 67–72 (2000). https://doi.org/10.1007/BF02677445

Download citation

  • Received:

  • Revised:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02677445

Keywords

Search

Navigation