Abstract
The growth of GaAs by chemical beam epitaxy using triethylgallium and trisdimethylaminoarsenic has been studied. Reflection high-energy electron diffraction (RHEED) measurements were used to investigate the growth behavior of GaAs over a wide temperature range of 300–550°C. Both group III- and group Vinduced RHEED intensity oscillations were observed, and actual V/III incorporation ratios on the substrate surface were established. Thick GaAs epitaxial layers (2–3 μm) were grown at different substrate temperatures and V/III ratios, and were characterized by the standard van der Pauw-Hall effect measurement and secondary ion mass spectroscopy analysis. The samples grown at substrate temperatures above 490°C showed n-type conduction, while those grown at substrate temperatures below 480°C showed p-type conduction. At a substrate temperature between 490 and 510°C and a V/III ratio of about 1.6, the unintentional doping concentration is n ∼2 × 1015 cm−3 with an electron mobility of 5700 cm2/V·s at 300K and 40000 cm2/V·s at 77K.
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A. Schütze, J. Zacheja, M. Weyers and D. Kohl,J. Cryst. Growth 107, 1036 (1991).
G.A. Miller,Solid State Technol. August, 59 (1989).
G.B. Stringfellow,J. Electron. Mater. 17, 327 (1988).
A. Brauers, O. Kayser, R. Kall, H. Heinecke, P. Balk and H. Hofmann,J. Cryst. Growth 93, 7 (1988).
R. Bhat, M.A. Koza and B.J. Skromme,Appl. Phys. Lett. 50, 1194(1987).
H.J. Moon, T.G. Stoebe and B.K. Chadwick,J. Electron. Mater. 19, 1351 (1990).
C.R. Abernathy, P.W. Wisk, D.A. Bohling and G.T. Muhr,Appl. Phys. Lett. 60, 2421 (1992).
C.R. Abernathy, P.W. Wisk, S.J. Pearton, F. Ren, D.A. Bohling and G.T. Muhr,J. Cryst Growth 124, 64 (1992).
S. Salim, J.P. Lu, K.F. Jensen and D.A. Bohling,J. Cryst. Growth 124, 16 (1992).
T. Koui, I. Suemune, K. Hamaoka, K. Fujii, A. Kishimoto, Y. Honda and M. Yamanishi,Ext. Abs. 1991 Intl. Conf. on Solid State Devices and Materials, Yokohama, (1991), p. 408.
K. Hamaoka, I. Suemune, K. Fujii, T. Koui, A. Kishimoto and M. Yamanishi,Jpn. J. Appl. Phys. 30, L1579 (1991).
K. Fujii, I. Suemune and M. Yamanishi,Appl. Phys. Lett. 61, 2577 (1992).
K. Fujii, I. Suemune, T. Koui and M. Yamanishi,Appl. Phys. Lett. 60, 1498 (1992).
T. Koui, I. Suemune, K. Miyakoshi, K. Fujii and M. Yamanishi,Jpn. J. Appl. Phys. 31, L1272 (1992).
G. Zimmermann, H. Protzmann, T. Marschner, O. Zsebök, W. Stolz, E.O. Göbel, P. Gimmnich, J. Lorberth, T. Filz, P. Kurpas and W. Richter,J. Cryst. Growth 129, 37 (1993).
M.H. Zimmer, R. Hovel, W. Brysch and A. Brauers,J. Cryst. Growth 107, 348 (1991).
H.K. Dong, B.W. Liang, M.C. Ho, S. Hung and C.W. Tu,J. Cryst. Growth 124, 181 (1992).
B.W. Liang, H.Q. Hou and C.W. Tu,Mater. Res. Soc. Symp. Proc. 222, 145 (1991).
D.A. Bohling, C.R. Abernathy and K.F. Jensen,J. Cryst. Growth 136, 118 (1994).
D.E. Hill,J. Appl. Phys. 41, 1815 (1970).
M.H. Kim, S.S. Bose, B.J. Skromme, B. Lee,and G.E. Stillman,J. Electron. Mater. 20, 671 (1991).
C. Hilsum,Electron Lett. 10, 259 (1974).
G.E. Stillman and C.M. Wolfe,Thin Solid Films 31,69 (1976).
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Dong, H.K., Li, N.Y., Tu, C.W. et al. A study of chemical beam epitaxy of GaAs using tris-dimethylaminoarsenic. J. Electron. Mater. 24, 69–74 (1995). https://doi.org/10.1007/BF02659623
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DOI: https://doi.org/10.1007/BF02659623