Abstract
Low-temperature reactions of benzyl halides with magnesium in the3P state proceed according to the radical mechanism accompanied by abstraction of the halogen atom by the biradical magnesium atom.
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G. B. Sergeev, V. V. Smirnov, and V. V. Zagorsky,J. Organomet. Chem., 1980,201, 9.
M. Moskovits and G. A. Ozin,Cryochemistry, Wiley, Chichester, 1976.
H. Gilman and R. E. Fortytrgiel,J. Am. Chem. Soc., 1928,50, 3334.
N. Ya. Buben, V. A. Tolkachev, and I. I. Chkheidze,Kinet. Katal., 1963,4, 683 [Kinet. Catal., 1963,4 (Engl. Transl.)].
V. A. Tolkachev, I. I. Chkheidze, and N. Ya. Buben,Dokl. Akad. Nauk SSSR, 1962,147, 643 [Dokl. Chem., 1962 (Engl. Transl.)].
P. Neta and R. H. Shuler,J. Phys. Chem., 1973,77, 1368.
A. M. Egorov and A. V. Anisimov,Appl. Organomet. Chem., 1995,9, 285.
S. V. Kombarova, L. A. Tyurina, and V. V. Smirnov,Metalloorg. Khim., 1992,5, 1038 [Organomet. Chem. USSR, 1992,5 (Engl. Transl.)].
A. Tuulmets, M. Khyrak, K. Sarv, and E. Aaresil'd,Reakts. Sposob. Org. Soed. [Reactivity Org. Compd.], 1985,22, 330 (in Russian).
M. S. Malinovskii and A. A. Yavorskii,Zh. Obshch. Khim., 1955,25, 2209 [J. Gen. Chem. USSR 1955,25 (Engl. Transl.)].
G. Brauer,Handbuch der Praeparativen Anorganischen Chemie, Enke Verlag, Stuttgart, Bd. 3, 1981.
T. Yokoyama, G. R. Wiley, and S. I. Miller,J. Org. Chem., 1969,64, 1859.
J. M. Aizpurua, B. Lecea, and C. Palomo,Can. J. Chem., 1969,64, 2342.
P. L. Timms,J. Chem. Educ., 1972,49, 782.
J. E. Dobson, P. M. Tucker, F. G. A. Stone, and R. Shaeffer.J. Chem. Soc. (A), 1969, 1882.
P. Caubere and J. Moreau,Tetrahedron, 1969,25, 2469.
J. Bergman,Tetrahedron, 1972,28, 3323.
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 147–151, January, 1999.
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Egorov, A.M., Anisimov, A.V. & Tarakanova, A.V. Low-temperature dehalogenation of benzyl halides with atomic magnesium in the3P state. Russ Chem Bull 48, 147–151 (1999). https://doi.org/10.1007/BF02494417
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DOI: https://doi.org/10.1007/BF02494417