Skip to main content
Log in

Effect of transition metal ions on partial ethane oxidation in an electrochemical system

  • Published:
Reaction Kinetics and Catalysis Letters Aims and scope Submit manuscript

Abstract

Transition metal ions (Fe2+ and Cu2+) have been found to enhance the rate of ethane partial oxidation in a gas-liquid electrochemical reactor under mild conditions (363 K, atmospheric pressure). The effect is discussed in terms of a radical-chain mechanism involving OH radicals.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. F. Frusteri, E.N. Savinov, A. Parmaliana, E.R. Savinova, V.N. Parmon, N. Giordano:Catal. Lett.,27, 355 (1994).

    Article  CAS  Google Scholar 

  2. A.O. Kuzmin, E.R. Savinova, V.N. Parmon:React. Kinet. Catal. Lett.,66, 351 (1999).

    CAS  Google Scholar 

  3. Q. Zhang, K. Otsuka:Chem. Lett., 363 (1997).

  4. A. Parmaliana, F. Frusteri, F. Arena, N. Giordano:Catal. Lett.,12, 353 (1992).

    Article  CAS  Google Scholar 

  5. A. Parmaliana:New Developments in Selective Oxidation, Vol. 55, p. 733, (G. Genti, F. Trifiró, Eds.). Elsevier, Amsterdam 1990.

    Google Scholar 

  6. J. Weiss:Advances in Catalysis and Related Subjects, vol. IV (W.G. Frankenburg, V.I. Komarewsky, E.K. Rideal, Eds.), 1952.

  7. J. Baxendale:Advances in Catalysis and Related Subjects, vol. IV (W.G. Frankenburg, V.I. Komarewsky, E.K. Rideal, Eds.), 1952.

  8. C. Walling:Accounts Chem. Res.,8, 125 (1975).

    Article  CAS  Google Scholar 

  9. Yu.N. Kozlov, A.D. Nadezhdin, A.P. Purmal:Kinetika i Kataliz,14, 141 (1973) (in Russian).

    CAS  Google Scholar 

  10. D. Dobos:Electrochemical Data. A Handbook for Electrochemists in Industry and Universities. Budapest, Akad. Kiadó 1978.

    Google Scholar 

  11. E.S. Rudakov:Reactions of Alkanes with Oxidants, Metal Complexes and Radicals in Solutions. Naukova Dumka, Kiev 1985 (in Russian).

    Google Scholar 

  12. V.M. Berdnikov, Yu.N. Kozlov, A.P. Purmal:Khimiya Vysokikh Energii,3, 321 (1969) (in Russian).

    CAS  Google Scholar 

  13. T.P. Vorobieva, V.M. Berdnikov, A.P. Purmal:Kinetika i Kataliz,11, 100 (1970) (in Russian).

    Google Scholar 

  14. E.R. Savinova, A.O. Kuzmin, F. Frusteri, A. Parmaliana, V.N. Parmon,Partial Oxidation of Ethane with Dioxygen in a Three-Phase Membrane Electrochemical Reactor, Studies Surface Science and Catalysis, Elsevier 1998.

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kuzmin, A.O., Savinova, E.R. & Parmon, V.N. Effect of transition metal ions on partial ethane oxidation in an electrochemical system. React Kinet Catal Lett 66, 359–366 (1999). https://doi.org/10.1007/BF02475813

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02475813

Keywords

Navigation