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Diene condensation on zeolites, II. Influence of the zeolite structure and the nature of substituting cation on the reaction of alloocimene with α-methacrolein

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Abstract

The interaction of alloocimene with α-methacrolein on β-zeolite with various substituent cations (Fe, Ni, Zn, Cu and La) as well as on ZSM-5, erionite and mordenite has been studied at room temperature in dichloromethane. Substituent cations in β-zeolite as well as the silica/alumina ratio and alkali metal content in the zeolite structure were found to affect the formation of ocinal diastereomers. Therefore, we assume that a complex of active sites participates in the diene condensation: Alkali metals present in the zeolite suppress the (3+2)-cycloaddition reaction.

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Authors and Affiliations

  1. Federal Scientific Center, Boreskov Institute of Catalysis, 630090, Novosibirsk, Russia

    T. G. Kuznetsova, K. G. Ione & N. V. Testova

  2. Institute of Organic Chemistry, 630090, Novosibirsk, Russia

    N. F. Salakhutdinov

Authors
  1. T. G. Kuznetsova
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  2. K. G. Ione
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  3. N. V. Testova
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  4. N. F. Salakhutdinov
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Kuznetsova, T.G., Ione, K.G., Testova, N.V. et al. Diene condensation on zeolites, II. Influence of the zeolite structure and the nature of substituting cation on the reaction of alloocimene with α-methacrolein. React Kinet Catal Lett 62, 287–291 (1997). https://doi.org/10.1007/BF02475465

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  • DOI: https://doi.org/10.1007/BF02475465

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