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Catalytic hydrogen transfer over magnesia, IXa. reduction of long chain aliphatic ketones by 2-propanol

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Abstract

A series of symmetrical long chain aliphatic ketones of general formula CH3−(CH2)n-CO-(CH2)2−CH3, where n=4,5,6,7 and 8, has been used as hydrogen acceptors from 2-propanol at 573–723 K in the presence of MgO catalyst under flow conditions. The yeilds of the appropriate alcohols exceeded 50%. Above 623 K the consecutive dehydration of the alcohols formed took place with moderate yields leading to internal alkenes. The direct one-step synthesis of C13 alkene from 7-tridecanone has been realized under catalytic transfer reduction (CTR) conditions with high yield (>90%) over a MgO catalyst of enhanced acidity.

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Authors and Affiliations

  1. Faculty of Chemistry, Laboratory of Catalytic Synthesis, Warsaw University of Technology (Politechnika), Koszykowa 75, 00-662, Warsaw, Poland

    M. Gliński

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  1. M. Gliński
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Correspondence to M. Gliński.

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Part VIII: Appl. Catal. A.:General,150, 77 (1997)

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Gliński, M. Catalytic hydrogen transfer over magnesia, IXa. reduction of long chain aliphatic ketones by 2-propanol. React Kinet Catal Lett 65, 121–129 (1998). https://doi.org/10.1007/BF02475325

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  • DOI: https://doi.org/10.1007/BF02475325

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