Skip to main content
SpringerLink
Log in

Quantitative analysis of apolar polysiloxane phases in large-bore capillary columns

  • Originals
  • Published:
Chromatographia Aims and scope Submit manuscript

Summary

A technique is described for determination of the amount of bonded phase in commercial columns. It is adapted to the determination of the real nature and the thickness of a siloxane bonded film. Ten-centimeter samples of column are used. The method is tested for large-bore capillary columns. Applications to kinetic studies are suggested.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Th. Tomas, T. Ckendrick, J. Polym. Sci.127, 537 (1969).

    Google Scholar 

  2. N. Grassie, N. Francy, Polym. Degr. Stab.2, 67 (1980).

    Article  CAS  Google Scholar 

  3. A. Balistrerei, G. Garzo, G. Montando, Macromolecules17, 1312 (1984).

    Article  Google Scholar 

  4. J. C. Kleinert, C. J. Wesher, Anal. Chem.52, 1245 (1980).

    Article  CAS  Google Scholar 

  5. J. Haken, N. Harahap, R. P. Burford, J. Chromatogr.387, 223 (1987).

    Article  CAS  Google Scholar 

  6. J. Franc, K. Placek, Coll. Czech. Chem. Commun.38, 513 (1973).

    CAS  Google Scholar 

  7. S. V. Kala, E. D. Lykissa, R. M. Lebovitz, Anal. Chem.69, 1267 (1997).

    Article  CAS  Google Scholar 

  8. G. W. Heylmun, J. E. Pikula, J. Gas Chromatogr.266 (1965).

  9. B. Souhail, Doctoral Dissertation, University Lyon 1, 1990.

  10. N. A. Palamarchuk, S. V. Syoustilla, L. A. nechaeva, Zhur. Anal. Khim., Engl. Transl.28, 2264 (1973).

    CAS  Google Scholar 

  11. H. S. Booth, M. L. Freedman, J., Am. Chem. Soc.72, 2847 (1950).

    Article  CAS  Google Scholar 

  12. J. F. Erard, E. Sz. Kovats, Anal. Chem.54, 193 (1982).

    CAS  Google Scholar 

  13. C. Gaget, D. Morel, M. Traore, J. Serpinet, Analusis12, 386 (1984).

    CAS  Google Scholar 

  14. G. Olah, J. Welch, Y. Yankas, M. Nojima, T. Kerekees, J. Olah, J. Org. Chem.44, 3872 (1979).

    Article  CAS  Google Scholar 

  15. M. Verzele, P. Mussche, P. Sandra, J. Chromatogr.190, 331 (1980).

    Article  CAS  Google Scholar 

  16. I. Temmerman, P. Sandra, M. Verzele, J. High Resol. Chromatogr. Chromatogr. Commun.8, 513 (1985).

    Article  CAS  Google Scholar 

  17. A. K Bemgard, L. G. Blomberg, A. L. Colmsjo, Anal. Chem.61, 2165 (1989).

    Article  Google Scholar 

  18. M. Saidi, Doctoral Dissertation, University Lyon 1, 1993.

  19. M. A. Kahn in M. Van Sway (Editor), Gas Chromatography 1962, Butterworth, London, 1962, 3–17.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Laboratoire des Sciences Analytiques, CNRS UMR 5619, 43 Bd du 11 Nov 1918, 69622, Villeurbanne Cedex, France

    D. Morel & J. Serpinet

  2. University of Algiers, Algeria

    M. Saidi

Authors
  1. D. Morel
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. M. Saidi
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. J. Serpinet
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Morel, D., Saidi, M. & Serpinet, J. Quantitative analysis of apolar polysiloxane phases in large-bore capillary columns. Chromatographia 47, 305–308 (1998). https://doi.org/10.1007/BF02466536

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02466536

Key Words

Search

Navigation