Abstract
Magnetic phase transitions in some new compounds of melilite structure\((P\overline 4 2_1 m)\) with extremely high iron content A2Fe2BO7 (A=Ba, Sr; B=Ge, Si) were observed at low temperatures by means of Mössbauer spectroscopy. It was found that Fe3+ magnetic moments are ordered by superexchange interaction in two sublattices with wide distributions of relatively low magnetic fields. The effect of Ba2+»Sr2+ and Ge4+»Si4+ cation substitutions on this magnetic ordering is discussed.
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Barb, D., Constantinescu, S., Tarina, D. et al. Magnetic hyperfine fields in ferrigehlenites. Hyperfine Interact 50, 645–650 (1989). https://doi.org/10.1007/BF02407703
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DOI: https://doi.org/10.1007/BF02407703