Abstract
The structure of aqueous solutions of 1,2-butanediol and 1,4-butanediol was investigated using adiabatic compressibility measurements and positron annihilation methods. In the case of 1,2-butanediol the experimental results are very similar to those obtained earlier for systems where hydrophobic hydration dominates. In both cases there are evidences for increased rigidity of the water network, which arises from the formation of hydrogen bonds between diols and water. The usefulness of both the methods applied in investigating the structure of liquid solutions was proved.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
H. S. Frank, M. W. Evans, J. Chem. Phys., 13 (1945) 478.
H. S. Frank, W. Y. Wen, Discuss. Faraday Soc., 24 (1957) 133.
D. W. Davidson, in: Water: A Comprehensive Treatise, Vol. 2,F. Franks (Ed), Plenum Press, 1973, Chap. 3, p. 115.
K. Jerie, A. Baranowski, B. Rozenfeld, J. Gliński, S. Ernst, Phys. Scripta, 35 (1987) 729 and papers cited therein.
Gy. Jákli, A. Baranowski, K. Jerie, J. Gliński, K. Orzechowski, Bull. Pol. Acad. Sci. Chem., 42 (1994) 71.
See for example:S. Ernst, J. Gliński, Mat. Sci., III/3 (1977) 69 (the system water+dioxane).
S. SH. Byk, Yu. F. Makogon, V. I. Fomina, in: Gazovye Gidraty, Izd. Khimia, Moscow, 1980, p. 12. For the collection of possible stoichiometries of clathrate hydrates see alsoYu. A. Dyadin, Supramolec. Chem., 6 (1995) 59.
A. Baranowski, K. Jerie, J. Gliński, K. Orzechowski, J. Radioanal. Nucl. Chem., 190 (1995) 469.
K. Jerie, A. Baranowski, B. Rozenfeld, S. Ernst, J. Gliński, Acta Phys. Polon., A64 (1983) 77.
S. Ernst, J. Gliński, B. Jezowska-Trzebiatowska, Acta Phys. Polon., A64 (1979) 501.
H. Endo, Bull. Chem. Soc. Japan., 16 (1973) 1586.
M. von Stackelberg, H. Müller, Z. Elektrochem., 58 (1954) 25.
Gy. Jákli, K. Jerie, A. Baranowski, J. Gliński, Acta Phys. Polon., A93 (1998) 649.
K. Jerie, A. Baranowski, S. Ernst, J. Gliński, Acta Phys. Polon., A69 (1986) 81.
M. Aratono, T. Toyomasu, M. Villeneuve, Y. Uchizono, T. Takiue, K. Motomura, N. Ikeda, J. Coll. Interface Sci., 191 (1997) 146. See alsoJ. Gliński, G. Chavepeyer, J.-K. Platten, J. Chem. Phys., to be published.
J. Gliński, G. Chavepeyer, J.-K. Platten, J. Chem. Phys., 104 (1996) 8816.
A. P. Buchikhin, V. J. Goldanski, A. O. Tatur, V. P. Shantarovich, Zh. Eksper. Teor. Fiz., 60 (1971) 1136; Sov. JETP, 33 (1971) 615.
S. J. Tao, J. Chem. Phys., 56 (1972) 5499.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Jerie, K., Baranowski, A., Gliński, J. et al. Investigation of the structure of aqueous solutions of 1,2-and 1,4-butanediol by positron annihilation and ultrasonic methods. J Radioanal Nucl Chem 241, 265–270 (1999). https://doi.org/10.1007/BF02347460
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF02347460