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Retention characteristics of fluorinated bonded silica phase in reversed-phase liquid chromatography

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Summary

Fluorinated bonded silica has been evaluated as a packing material in reversed-phase liquid chromatography (RPLC) with polycyclic aromatic hydrocarbons, chlorinated benzenes and substituted benzenes as sample probes. The bonded material is useful as a reversed-phase stationary phase and for polar compounds it offers a specific selectivity not found with octadecylsilica (ODS) phases. The phase also retains non-planar compounds more than planar molecules. The results can be explained by conformational differences between ODS and the fluorinated bonded phase by MM2 calculation.

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References

  1. L. C. Sander, S. A. Wise, CRC Critical Review in Anal. Chem.18, 299 (1987).

    Google Scholar 

  2. A. Haas, J. Kohler, H. Hemetsberger, Chromatographia14, 341 (1981).

    Google Scholar 

  3. C. Hirayama, H. Ihara, S. Nagaoka, K. Hamada, J. Chromatogr.465, 241 (1989).

    Google Scholar 

  4. G. Xindu, P. W. Carr, J. Chromatogr.269, 96 (1983).

    Google Scholar 

  5. H. A. Billet, P. J. Schoemarkers, L. De Galan, J. Chromatogr.218, 443 (1983).

    Google Scholar 

  6. T. Konakahara, S. Okada, T. Monde, N. Nakayama, J. Furuhashi, J. Sugaya, J. Chem. Soc. Japan (Nikkashi)12, 1638 (1991).

    Google Scholar 

  7. J. F. Schabron, R. J. Hurtubise, H. F. Silver, Anal. Chem.49, 2253 (1977).

    Google Scholar 

  8. S. A. Wise, W. J. Bonnett, F. R. Guenther, W. E. May, J. Chromatogr. Sci.19, 475 (1981).

    Google Scholar 

  9. A. Radecki, H. Lamparczyk, R. Kaliszan, Chromatographia12, 495 (1979).

    Google Scholar 

  10. L. C. Sander, S. A. Wise, LC.GC8, 378 (1990).

    Google Scholar 

  11. L. C. Sander, S. A. Wise, Anal. Chem.56, 504 (1984).

    Google Scholar 

  12. S. A. Wise, L. C. Sander, HRC & CC8, 248 (1985).

    Google Scholar 

  13. L. C. Sander, S. A. Wise, Anal. Chem.59, 2309 (1987).

    Google Scholar 

  14. K. Jinno, T. Ibuki, N. Tanaka, M. Okamoto, J. C. Fetzer, W. R. Biggs, P. R. Griffiths, J. M. Olinger, J. Chromatogr.461, 209 (1989).

    Google Scholar 

  15. K. Jinno, T. Nagoshi, N. Tanaka, M. Okamoto, J. C. Fetzer, W. R. Biggs, J. Chromatogr.392, 75 (1987).

    Google Scholar 

  16. K. Jinno, S. Shimura, N. Tanaka, K. Kitami, J. C. Fetzer, W. R. Biggs, Chromatographia27, 285 (1989).

    Google Scholar 

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Authors and Affiliations

  1. School of Materials Science, Toyohashi University of Technology, 441, Toyohashi, Japan

    K. Jinno & H. Nakamura

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  1. K. Jinno
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  2. H. Nakamura
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Jinno, K., Nakamura, H. Retention characteristics of fluorinated bonded silica phase in reversed-phase liquid chromatography. Chromatographia 39, 285–293 (1994). https://doi.org/10.1007/BF02274515

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  • DOI: https://doi.org/10.1007/BF02274515

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