Skip to main content
SpringerLink
Log in

Graphitized thermal carbon black as a shape-selective stationary phase in GC

  • Originals
  • Published:
Chromatographia Aims and scope Submit manuscript

Summary

The adsorption of moelcules on the nonspecific and nonporous adsorbent graphitized thermal carbon black (GTCB) is mainly determined by their intermolecular dispersion interaction with the flat graphite surface. Since the retention values strongly depend on the geometrical configuration and shape of the investigated molecules and their arrangement on the graphite plane, it is possible to separate compounds with only small differences in their molecular shape on short columns packed with particles of pure or modified GTCB.

The outstanding shape-selectivity of GTCB toward isomeric hydrocarbons is demonstrated by some examples.

In most cases the elution sequences of isomeric compounds differ from that obtained in GLC using nonpolar stationary liquids. Moreover, the well defined relationship between retention data and molecular structure by adsorption on a flat and homogeneous surface give useful information for the identification of separated compounds or for the investigation of the molecular structure.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. J. Halasz, C. Horvath, Nature197, 71 (1963).

    Google Scholar 

  2. C. Vidal-Madjar, G. Guiochon, Separation and Purification Methods2, 1 (1973).

    Google Scholar 

  3. A. Di Corcia, A. Liberti, in Advances in Chromatography,C. Giddings, ed., Vol.14, M. Dekker, New York 1976, p. 305.

    Google Scholar 

  4. A. V. Kiselev, Ja. J. Jasin, Gas- und Flüssigkeits-Adsorptionschromatographie, VEB Deutscher Verlag der Wissenschaften, Berlin (1985).

  5. N. N. Avgul, A. V. Kiselev, in Chemistry and Physics of Carbon,P. L. Walker, ed., Vol.6, Marcel Dekker, New York (1970).

    Google Scholar 

  6. A. V. Kiselev, J. Chromatogr.49, 84 (1970).

    Google Scholar 

  7. F. Bruner, G. Bertoni, P. Ciccioli, J. Chromatogr.120, 307 (1976).

    Google Scholar 

  8. C. A. Cramers, J. A. Rijks, in Advances in Chroamatography, Vol. 17,J. C. Giddings, E. grushka, J. Cazes, Ph. R. Brown, eds., Marcel Dekker, New York/Basel 1979, p. 101.

    Google Scholar 

  9. Xiang Min, F. Bruner, J. Chromatogr.468, 365 (1989).

    Google Scholar 

  10. C. Vidal-Madjar, F. Ganansia, G. Guiochon, Proc. of the 8th Intern. Symp. on Gas Chroamtography 1970,R. Scott, ed., Institute of Petroleum 1971, p. 20.

  11. G. Goretti, A. Liberti, G. Pili, J. High Resolut. Chrom.9, 143 (1978).

    Google Scholar 

  12. C. Vidal-Madjar, S. Bekassy, M. F. Gonnord, P. Arpino, G. Guiochon, Anal. Chem.49, 768 (1977).

    Google Scholar 

  13. F. Bruner, G. Crescentini, F. Mangani, P. Palma, M. Xiang, J. Chromatogr.399, 87 (1987).

    Google Scholar 

  14. F. Bruner, P. Ciccioli, G. Bertoni, A. Liberti, J. Chromatogr. Sci.12, 758 (1974).

    Google Scholar 

  15. F. Bruner, P. Ciccioli, G. Bertoni, J. Chromatogr.90, 239 (1974).

    Google Scholar 

  16. T. Welsch, W. Engewald, J. Pörschmann, J. prakt. Chem.320, 493 (1978).

    Google Scholar 

  17. A. V. Kiselev, V. J. Nazarova, K. D. Schcherbakova, Chromatographia14, 148 (1981).

    Google Scholar 

  18. T. Welsch, W. Engewald, J. Pörschmann, J. Chromatogr.148, 143 (1978).

    Google Scholar 

  19. H. H. Lauer, H. Poppe, J. F. K. Huber, J. Chromatogr.132, 1 (1977).

    Google Scholar 

  20. O. G. Eisen, A. V. Kiselev, A. E. Pilt, S. A. Rang, K. D. Shcherbakova, Chromatographia4, 448 (1971).

    Google Scholar 

  21. S. A. Rang, O. G. Eisen, A. V. Kiselev, A. E. Meister, K. D. Shcherbakova, Chromatographia8, 327 (1975).

    Google Scholar 

  22. O. Eisen, A. Orav, S. Rang, Chromatographia5, 229 (1972).

    Google Scholar 

  23. E. V. Kalashnikova, A. V. Kiselev, K. D. Shcherbakova, J. S. Zamanskaja, Chromatographia5, 278 (1972).

    Google Scholar 

  24. W. Engewald, J. Pörschmann, T. Welsch, K. D. Shcherbakova, Z. Chem.17, 375 (1977).

    Google Scholar 

  25. W. Engewald, K. Epsch, J. Graefe, T. Welsch, J. Chromatogr.94, 623 (1974).

    Google Scholar 

  26. W. Engewald, E. V. Kalashnikova, A. V. Kiselev, R. S. Petrova, K. D. Shcherbakova, A. L. Shilov, J. Chromatogr.152, 453 (1978).

    Google Scholar 

  27. W. Engewald, U. Billing, T. Welsch, G. Haufe, Chromatographia32, 590 (1987).

    Google Scholar 

  28. E. V. Kalashnikova, A. V. Kiselev, K. D. Shcherbakova, Chroamtographia7, 22 (1974).

    Google Scholar 

  29. E. V. Kalashnikova, A. V. Kiselev, R. S. Petrova, K. D. Shcherbakova, D. P. Poshkus, Chromatographia12, 799 (1979).

    Google Scholar 

  30. A. K. Kalashnikova, A. V. Kiselev, K. D. Shcherbakova, S. D. Vasileva, Chromatographia13, 493 (1980).

    Google Scholar 

  31. A. K. Kiselev, N. S. Kulikov, G. Curthoys, Chromatographia18, 297 (1984).

    Google Scholar 

  32. E. V. Kalashnikova, A. V. Kiselev, K. D. Shcherbakova, S. D. Vasileva, Chromatographia14, 510 (1981).

    Google Scholar 

  33. W. Engewald, L. Wennrich, E. Ritter, J. Chromatogr.174, 315 (1979).

    Google Scholar 

  34. W. Engewald, L. Wennrich, J. Pörschmann, Chromatographia11, 434 (1978).

    Google Scholar 

  35. W. Engewald, J. Topalova, N. Petsev, Chr. Dimitrov, Chromatographia23, 561 (1987).

    Google Scholar 

  36. F. Bruer, G. Grescentini, F. Mangani, Pure & Appl. Chem.61, 1987 (1989).

    Google Scholar 

  37. E. W. Pitzer, J. Chromatogr. Sci.26, 223 (1988).

    Google Scholar 

  38. W. Engewald, T. Maurer, A. Schiefke, Pure & Appl. Chem.61, 2001 (1989).

    Google Scholar 

  39. W. Engewald, T. Maurer, J. Chromatogr., in press (1990).

  40. W. Engewald, J. Graefe, A. V. Kiselev, K. D. Shcherbakova, T. Welsch, Chromatographia7, 229 (1974).

    Google Scholar 

  41. E. V. Kalashnikova, A. V. Kiselev, D. P. Poshkus, K. D. Shcherbakova, J. Chromatogr.119, 233 (1976).

    Google Scholar 

  42. C. Vidal-Madjar, M. F. Gonnord, G. Guiochon, J. Colloid and Interface Sci.52, 102 (1975).

    Google Scholar 

  43. M. F. Gonnord, C. Vidal-Madjar, G. Guiochon, J. Chromatogr. Sci.12, 839 (1974).

    Google Scholar 

  44. D. P. Poshkus, A. J. Grumadas, J. Chromatogr.191, 169 (1980).

    Google Scholar 

  45. E. V. Kalashnikova, A. V. Kiselev, K. D. Shcerbakova, Chroamtographia17, 521 (1983).

    Google Scholar 

  46. A. V. Kiselev, V. I. Nazarova, K. D. Shcherbakova, E. Smolkova-Keulemansova, L. Feltl, Chromatographia17, 533 (1983).

    Google Scholar 

  47. A. V. Kiselev, Chromatographia11, 691 (1978).

    Google Scholar 

  48. R. A. Hively, R. E. Hinton, J. Gas Chromatogr.6, 203 (1968).

    Google Scholar 

  49. A. J. Lubeck, D. L. Sutton, J. High Resolut. Chromatogr. & Chromatogr. Commun.6, 328 (1983).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Analytical Centre, Karl-Marx-University of Leipzig, Talstraße 35, 7010, Leipzig, Germany

    W. Engewald & T. Welsch

  2. Institute of Chemical Toxicology, Academy of Sciences, Permoser Str. 15, 7050, Leipzig, Germany

    J. Pörschmann

Authors
  1. W. Engewald
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. J. Pörschmann
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. T. Welsch
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Engewald, W., Pörschmann, J. & Welsch, T. Graphitized thermal carbon black as a shape-selective stationary phase in GC. Chromatographia 30, 537–542 (1990). https://doi.org/10.1007/BF02269801

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02269801

Key Words

Search

Navigation