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Oxidative bromination of olefins catalyzed by thallium(III) and heteropolyacids in aqueous solutions

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Abstract

The system TlIII+HPA-n, where HPA-n is the heteropolyacid H3+nPMo12−nVnO40 with n=2−8, in the presence of O2 is found to be a homogeneous catalyst for the oxidative bromination of olefins by Br− ions in aqueous solutions.

Abstract

Показано, что система TlIII+HPA-n, где HPA-n — гетерополикислоты H3+nPMo12−nVnO40 с n=2−8, в присутствии O2 являются гомогенным катализатором окислительного бромирования олефинов ионами Br− в водном растворе.

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Authors and Affiliations

  1. Institute of Catalysis, Novosibirsk, USSR

    T. A. Gorodetskaya, I. V. Kozhevnikov & K. I. Matveev

Authors
  1. T. A. Gorodetskaya
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  2. I. V. Kozhevnikov
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  3. K. I. Matveev
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Gorodetskaya, T.A., Kozhevnikov, I.V. & Matveev, K.I. Oxidative bromination of olefins catalyzed by thallium(III) and heteropolyacids in aqueous solutions. React Kinet Catal Lett 16, 17–18 (1981). https://doi.org/10.1007/BF02077021

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  • DOI: https://doi.org/10.1007/BF02077021

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