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ESR studies of ethylene interaction with active sites of supported organometallic catalysts for ethylene polymerization

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Abstract

Peculiarities of ethylene interaction with surface alkyl compounds of Ti3+ in catalysts for ethylene polymerization prepared via the reaction between tetrabenzyltitanium and silica have been studied by the ESR method.

Abstract

Методом ЭПР изучены особенности взаимодействия этилена с поверхностными алкильными соединениями Ti3+ в катализаторах полимеризации этилена, приготовленных взаимодействием тетрабензилтитана с силикагелем и активированных УФ-облучением.

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References

  1. D.G.H. Ballard: Adv. Catal.,23, 163 (1973).

    Google Scholar 

  2. Yu.I. Yermakov, V.A. Zakharov: Adv. Catal.,24, 173 (1975).

    Google Scholar 

  3. O.A. Efimov, A.I. Minkov, V.A. Zakharov, Yu.I. Yermakov: Kinet. Katal.,4, 995 (1976).

    Google Scholar 

  4. G.A. Nesterov, V.A. Zakharov, N.G. Maksimov, V.K. Dudchenko, S.B. Golshtein, I.Sh. Guzman, Yu.I. Yermakov: Vysokomol. Soedin., Ser. B,22, 808 (1980).

    Google Scholar 

  5. N.G. Maksimov, G.A. Nesterov, V.A. Zakharov, P.V. Schastnev, V.F. Anufrienko, Yu.I. Yermakov: J. Molec. Catal.,4, 167 (1978).

    Google Scholar 

  6. N.G. Maksimov, V.K. Dudchenko, V.F. Anufrienko, V.A. Zakharov, Yu.I. Yermakov: Zh. Teor. Eksp. Khim.,14, 55 (1978).

    Google Scholar 

  7. U. Zuccini, E. Albazzati, U. Giannini: J. Organomet. Chem.,29, 357 (1971).

    Google Scholar 

  8. J.W. Bassi, G. Allegra, R. Scordamaglia, G. Choiccola: J. Amer. Chem. Soc.,93, 3787 (1971).

    Google Scholar 

  9. M.A. Kuska, M.T. Rogers: J. Chem. Phys.,43, 1744 (1965).

    Google Scholar 

  10. F.S. Gadzhieva, V.F. Anufrienko, G.K. Boreskov: Dokl. Akad. Nauk SSSR,265, 638 (1982).

    Google Scholar 

  11. F.S. Gadzhieva, V.F. Anufrienko: Zh. Strukt. Khim.,5, 43 (1982).

    Google Scholar 

  12. A.A. Shklyaev, V.F. Anufrienko, Yu.N. Molin, E.I. Berus: Dokl. Akad. Nauk SSSR,207, 138 (1972).

    Google Scholar 

  13. S.A. Altshuler, B.Sh. Kozyrev: Electron-Paramagnetic Resonance of Transition Metal Compounds, Nauka, Moskva 1972.

    Google Scholar 

  14. N.G. Maksimov, E.G. Ismagilov: Teor. Eksp. Khim.,11, 260 (1975).

    Google Scholar 

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Authors and Affiliations

  1. Institute of Catalysis, Novosibirsk, USSR

    V. A. Poluboyarov, G. A. Nesterov, V. A. Zakharov & V. P. Anufrienko

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  1. V. A. Poluboyarov
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  2. G. A. Nesterov
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  3. V. A. Zakharov
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  4. V. P. Anufrienko
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Poluboyarov, V.A., Nesterov, G.A., Zakharov, V.A. et al. ESR studies of ethylene interaction with active sites of supported organometallic catalysts for ethylene polymerization. React Kinet Catal Lett 25, 33–38 (1984). https://doi.org/10.1007/BF02076535

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  • DOI: https://doi.org/10.1007/BF02076535

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