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Competitive hydrogenations over a ruthenium catalyst

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Abstract

Hydrogenations of three individual substrates (α-methylstyrene, benzaldehyde, cyclohexanone) were carried out on a ruthenium catalyst. On the basis of these results, selectivities of competitive hydrogenations of α-methylstyrene-benzaldehyde, benzaldehyde-cyclohexanone and α-methylstyrene-cyclohexanone binary mixtures were evaluated. It was shown that the reactivity of individual substrates could be substantially different when hydrogenated competitively with another compound in a binary system.

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Kluson, P., Kacer, P. & Cerveny, L. Competitive hydrogenations over a ruthenium catalyst. React Kinet Catal Lett 59, 263–268 (1996). https://doi.org/10.1007/BF02068122

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  • DOI: https://doi.org/10.1007/BF02068122

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