Abstract
Hydrogenations of three individual substrates (α-methylstyrene, benzaldehyde, cyclohexanone) were carried out on a ruthenium catalyst. On the basis of these results, selectivities of competitive hydrogenations of α-methylstyrene-benzaldehyde, benzaldehyde-cyclohexanone and α-methylstyrene-cyclohexanone binary mixtures were evaluated. It was shown that the reactivity of individual substrates could be substantially different when hydrogenated competitively with another compound in a binary system.
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References
P. Kluson, L. Cerveny:Appl. Catal.,128, 13 (1995).
Ch. Minot, P. Gallezot:J. Catal.,123, 341 (1990).
L. Cerveny, V. Heral, A. Marhoul, V. Ruzicka:Chem. Listy,68, 1286 (1977).
L. Cerveny, V. Ruzicka:Catal. Rev.-Sci. Eng.,24, 503 (1982).
C.H.P. Rader, H.A. Smith:J. Am. Chem. Soc.,84, 1443 (1982).
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Kluson, P., Kacer, P. & Cerveny, L. Competitive hydrogenations over a ruthenium catalyst. React Kinet Catal Lett 59, 263–268 (1996). https://doi.org/10.1007/BF02068122
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DOI: https://doi.org/10.1007/BF02068122