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High-resolution solid-state27Al NMR studies of aluminium coordination in acidic catalysts

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Abstract

Chemical shifts of tetrahedrally and octahedrally coordinated aluminium in various crystal and amorphous compounds have been determined by high-resolution solid-state27Al NMR. A similarity between chemical shifts of aluminium in amorphous and crystalline compounds of the same composition has been revealed. For binary compounds the chemical shifts are in a linear relationship with the electronegativity of elements bonded to aluminium-oxygen polyhedra.

Abstract

Методом ЯМР27Al высокго разрешения в твердом теле определены химические сдвиги тетраэдрически и октаэдрически координированного алюминия в кристаллических и аморфных соединениях разичных классов. Показана близость химических сдвигов алюминия в аморфных и кристаллических веществах одинакового состава. Для бинарных соединений установлена линейная связь между химическим сдвигом и электроотрицательностью элементов, связанных с алюмокислородными полиэдрами.

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References

  1. D. Müller, W. Gessner, A.-R. Grimmer: Z. Chem.,17, 453 (1977)

    Google Scholar 

  2. D. Müller, W. Gessner, H.-J. Behrens, G. Scheler: Chem. Phys. Lett.,79, 59 (1981)

    Google Scholar 

  3. V.M. Mastikhin, O.P. Krivoruchko, B.P. Zolotovskii, R.A. Buyanov: React. Kinet. Catal. Lett.,18, 117 (1981)

    Google Scholar 

  4. D. Freude, H.-J. Behrens: Cryst. Res. Techn.,16, K36 (1981)

    Google Scholar 

  5. C.A. Fyfe, G.C. Gobbi, J.S. Hartman, J. Klinowski, J.M. Thomas: J. Phys. Chem.,86, 1247 (1982)

    Google Scholar 

  6. D. Müller, I. Grunze, E. Hallas, G. Ladwig: Z. anorg. Allg. Chem.,500, 80 (1983)

    Google Scholar 

  7. W. Schiller, D. Müller, G. Scheler: Z. Chem.,22, 44 (1982)

    Google Scholar 

  8. V.A. Dzisko, A.P. Karnaukhov, D.V. Tarasova: Physico-Chemical Fundamentals for the Synthesis of Oxide Catalysts. Nauka, Novosibirsk 1978

    Google Scholar 

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Authors and Affiliations

  1. Institute of Catalysis, 630090, Novosibirsk, USSR

    N. S. Kotsarenko, V. M. Mastikhin, I. L. Mudrakovskii & V. P. Shmachkova

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  1. N. S. Kotsarenko
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  2. V. M. Mastikhin
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  3. I. L. Mudrakovskii
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  4. V. P. Shmachkova
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Kotsarenko, N.S., Mastikhin, V.M., Mudrakovskii, I.L. et al. High-resolution solid-state27Al NMR studies of aluminium coordination in acidic catalysts. React Kinet Catal Lett 30, 375–382 (1986). https://doi.org/10.1007/BF02064316

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  • DOI: https://doi.org/10.1007/BF02064316

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