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Studies of immobilized V−P/SiO2 catalysts

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Abstract

It has been revealed that simultaneous immobilization of vanadium and phosphorus ions increases the activity and selectivity of vanadium-containing aerosils in n-butane oxidation. The catalytic properties are suggested to be dependent on the formation of mixed oxide surface V−P/SiO2 clusters having optimal acid-base characteristics.

Abstract

Показано, что совместная прививка ионов ванадия и фосфоа увеличивает активность и селективность ванадийсодержащих азросилов в реакции окисления н-бутана. Высказано предположение о связи каталитических свойств с образованием окисных группировок, содержащих ванадий и фофор с оптимальными кислотно-основными свойствами.

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References

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Authors and Affiliations

  1. Institute of Physical Chemistry, 252028, Kiev, USSR

    V. A. Zazhigalov, Yu. P. Zaitsev & V. M. Belousov

  2. Central Institute of Physical Chemistry, 1199, Berlin, GDR

    B. Parlitz, W. Hanke & G. Öhlmann

Authors
  1. V. A. Zazhigalov
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  2. Yu. P. Zaitsev
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  3. V. M. Belousov
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  4. B. Parlitz
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  5. W. Hanke
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  6. G. Öhlmann
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Zazhigalov, V.A., Zaitsev, Y.P., Belousov, V.M. et al. Studies of immobilized V−P/SiO2 catalysts. React Kinet Catal Lett 32, 209–214 (1986). https://doi.org/10.1007/BF02063474

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  • DOI: https://doi.org/10.1007/BF02063474

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