Abstract
Catalystic properties of Group VIII transition metals and Cu, Ag, Au and Hg compounds in diethylketon synthesis from ethylene, carbon monoxide and hydrogen in concentrated aqueous solutions of trifluoroacetic acid containing triphenylphosphine have been examined in mild conditions (70°C, 1 bar). It has been established that under these conditions, in addition to Pd axcetate, a noticeable activity in diethylketone synthesis is observed only for Pt and Rh compounds.
Abstract
Исследованы каталитические свойства соединений переходных металлов VIII группы, а также Cu, Ag, Au и Hg в реакции синтеза диэтилкетона из этилена, окиси углерода и водорода в концентрированном водном растворе трифторуксусной кислоты, содержащем трифенилфосфин, в мягких условиях (70°C, 1 бар). Установлено, что в этих условиях кроме ацетата Pd только соединения Pt и Rh проявляют заметную активность в синтезе диэтилкетона.
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Ilinich, G.N., Zudin, V.N., Likholobov, V.A. et al. Reactive properties of phosphine complexes of some transition metals in ethylene carbonylation. React Kinet Catal Lett 31, 61–64 (1986). https://doi.org/10.1007/BF02062512
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DOI: https://doi.org/10.1007/BF02062512