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Properties of silica-supported Pt−Mo and Pd−Mo catalysts obtained from organometallic compounds

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Abstract

An assumption has been made on the possibility of stabilizing highly dispersed metal particles in the presence of low-valent transition metal ions bound to the carrier. This assumption is supported by studies of the dispersion and catalytic activity of Pt−Mo and Pd−Mo catalysts obtained from π-allyl complexes of Mo, Pt, Pd.

Abstract

Сделано предположение о возможности стабилизации выс окодисперс ных частиц металлов в присутствии низковалентных ионов переходных элементов, связанных с носителем. Изучение дисперености и каталитическ ои активности Pt−Mo и Pd−Mo катализаторов, полученных с использованием π-аллильных комплексов Mo, Pt и Pd, подтверждает это предполозение.

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Yermakov, Y.I., Kuznetsov, B.N. & Ryndin, Y.A. Properties of silica-supported Pt−Mo and Pd−Mo catalysts obtained from organometallic compounds. React Kinet Catal Lett 2, 151–161 (1975). https://doi.org/10.1007/BF02060966

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  • DOI: https://doi.org/10.1007/BF02060966

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