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Thermoanalytical evaluation of readily available reference polymers

Thermoplastics

  • Polymers
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Abstract

A commercial set of polymers has been characterized by TG-DTA, DSC, TMA, FTIR spectroscopy and X-ray diffraction analysis (XRD). Thermal and mechanical stability, as well as the polymer glass transition temperature,T g, and melt temperature,T m, have been documented. There is a good correlation between measuredT g andT m values and published data. The degree of polymer crystallinity for polyethylene has been verified by XRD. The credibility and stability of these reference polymers is based on a comparison of their thermal properties, over a wide range of temperatures from two versions of a reference set, published in 1979 (A) and 1994 (B). The thermal properties and crystallinity of these polymers have stood the test of time and are reliable, readily available and consistent.

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References

  1. ASTM Committee E37.02, Thermal Methods — Standard Reference Materials, ASTM Directory, 1993, p. 109.

  2. ASTM Committee D20.94.02, Plastics-Standardization of Test Specimens, D20.30, Thermal Properties, 1993, p. 83.

  3. A. D. Murray, Engineering Plastics, ASM International, 2 (1988) 277.

    Google Scholar 

  4. J. H. Crate, Engineering Plastics, ASM International, 2 (1988) 651.

    Google Scholar 

  5. J. M. Margolis, Engineering Plastics, ASM International, 2 (1988) 97.

    Google Scholar 

  6. A. Riga, Am. Chem. Soc., Educational Course, (1992–1995) 1–472.

  7. R. Lebeaux, The Resinkit®, 1112 River St., Woonsocket, RI 02895.

  8. Phillips Electronic Instruments Co., X-Ray Diffraction X-Pert System, Mahwah, NJ 07430.

  9. TG/DTA Robotic System and TMA SS, Haake Seiko Instruments, Washingtonville, NY 10992.

  10. Annual Book of ASTM Standards, General Methods and Instrumentation, 14.02. E1582-93 1995, p. 933.

  11. Annual Book of ASTM Standards, General Methods and Instrumentation, 14.02, E 1363-95, 855 and E794-95 1996, p. 531.

  12. DSC 2000, TA Instruments, New Castle, DE 19720.

  13. Mattson FTIR Spectrometer.

  14. A. T. Riga and E. A. Collins, Engineering Plastics, ASM International, 2 (1988) 824.

    Google Scholar 

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Riga, A., Young, D., Mlachak, G. et al. Thermoanalytical evaluation of readily available reference polymers. Journal of Thermal Analysis 49, 425–435 (1997). https://doi.org/10.1007/BF01987466

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  • DOI: https://doi.org/10.1007/BF01987466

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