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Thermochemistry of interactions of Na+ with benzo-15-crown-5 ether in acetonitrile-water mixtures at 298.15 K

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Abstract

Enthalpies of dissolution of benzo-15-crown-5 ether (B15C5) in mixtures of acetonitrile with water and in solutions of NaI and NaBPh4 (I=0.05 mol dm−3) in these mixtures were measured at 298.15 K. From the obtained results and appropriate literature data, the thermodynamic functions of B15C5/Na+ complex formation in acetonitrile-water mixtures were determined. The enthalpies of transfer of the complex B15C5/Na+ from pure acetonitrile to the examined mixtures were calculated and are discussed.

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Authors and Affiliations

  1. Department of Physical Chemistry, University of Łódz, Pomorska 165, 90-236, Łódz, Poland

    H. Piekarski & Malgorzata Józwiak

Authors
  1. H. Piekarski
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  2. Malgorzata Józwiak
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Piekarski, H., Józwiak, M. Thermochemistry of interactions of Na+ with benzo-15-crown-5 ether in acetonitrile-water mixtures at 298.15 K. Journal of Thermal Analysis 48, 1283–1291 (1997). https://doi.org/10.1007/BF01983438

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  • DOI: https://doi.org/10.1007/BF01983438

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