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Enthalpies of dilution for 1∶3 and 3∶1 electrolytes aqueous solutions

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Abstract

The enthalpies of dilution for aqueous solutions of [Co(cn)3)]Cl3, [Co(pn)3)]Cl3 and [Co(tn)3]Cl3, (whereen=1,2-diaminoethane,pn=1,2-diaminopropane, andtn=1,3-diaminopropane) have been measured at 298.15 K, and up to 1 mol kg−1+, using a new large isoperibol calorimeter by the “long-jump” method. Relative apparent molar enthalpies,291-01, have been extracted as an empirical equation relatingL Φ andm. We have compared our complex salts with the 3∶1 and 1∶3 aqueous systems found in the literature. Theoretical predictions for 1∶3 and 3∶1 electrolytes in the Restricted Primitive Model are also shown.

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References

  1. F. H. Spedding, M. A. Mohs, J. L. Derer and A. Habenschuss, J. Chem. Eng. Data. 22 (1977) 142.

    Article  Google Scholar 

  2. K. S. Pitzer, J. R. Peterson and L. F. Silvester, J. Solution Chem., 7 (1978) 45.

    Article  Google Scholar 

  3. P. F. van Gaans and J. van Miltenburg, J. Solution Chem., 20 (1991) 335.

    Article  Google Scholar 

  4. C. E. Vanderzee and D. L. King, J. Chem. Thermodynamics, 11 (1979) 25.

    Article  Google Scholar 

  5. E. Lange and W. Miederer, Z. Elektrochem., 60 (1956) 34.

    Google Scholar 

  6. E. Lange and D. Secrest, Z. Elektrochem., 61 (1957) 280.

    Google Scholar 

  7. J. M. Arsuaga, Doctoral Thesis, Univ. Complutense, Madrid 1994.

    Google Scholar 

  8. J. M. Arsuaga, F. Fernández-Martín and J. Núñez, J. Solution Chem., in press.

  9. A. P. Brunetti, E. J. Prosen and R. N. Goldberg, J. Res. Nat. Bur. Stand. (U.S.), 77A (1973) 599.

    Google Scholar 

  10. V. B. Parker, Thermal Properties of Aqueous Uni-Univalent Electrolytes, NSRDS-NBS 2, Washington D. C. 1965.

  11. F. Malatesta, Gazz. Chim. Ital., 113 (1983) 783.

    Google Scholar 

  12. J. C. Rasaiah, J. Solution Chem., 2 (1973) 301.

    Article  Google Scholar 

  13. S.-H. Suh, L. Mier-Y-Teran, H. S. White and H. T. Davis, Chem. Phys., 142 (1990) 203.

    Article  Google Scholar 

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Authors and Affiliations

  1. Departamento de Química-Física I, Facultad de Quimica, Universidad Complutense, 28040, Madrid

    J. M. Arsuaga & J. Núñez

  2. Instituto del Frío, C.S.I.C., 28040, Madrid, Spain

    F. Fernández-Martín

Authors
  1. J. M. Arsuaga
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  2. F. Fernández-Martín
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  3. J. Núñez
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Additional information

This work was supported in part by CICYT (M.E.C., Spain) under Research Project No.: PB92-0553.

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Arsuaga, J.M., Fernández-Martín, F. & Núñez, J. Enthalpies of dilution for 1∶3 and 3∶1 electrolytes aqueous solutions. Journal of Thermal Analysis 47, 291–297 (1996). https://doi.org/10.1007/BF01982708

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  • DOI: https://doi.org/10.1007/BF01982708

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