Abstract
Malonate, succinate and glutarate of yttrium were obtained by dissolving Y(OH)3 in a solution of the corresponding acid and crystallization, whereas adipate, pimelate, suberate, azelate and sebacate in the reaction of YCl3 with the ammonium salt of the acid. Yttrium alkanodicarboxylates were prepared as crystalline solids with general formula Y2O3.nH2O, wheren=3, 4, 6, 7. On the basis of IR spectra the way of coordination COO− - Y3+ was established. Yttrium malonate, succinate, glutarate, azelate and sebacate heated lose crystallization water and next anhydrous complexes are transformed to Y2O3, whereas yttrium adipate, pimelate and suberate on heating lose some water molecules and, the mono- or dihydrates formed are decomposed to Y2O3. The properties of the studied complexes change discretely according to odd or even number of carbon atoms in the chain.
Zusammenfassung
Durch Auflösen von Y(OH)3 in einer Lösung der entsprechenden Säure und anschliessendem Kristallisieren wurden Yttriummalonat,-succinat und -glutarat dargestellt, das Yttriumadipat, -pimelat-, -suberat und -azelainat und sebacate hingegen in der Reaktion von YCl3 mit dem Ammoniumsalz der Säure. In Form kristalliner Feststoffe wurden Yttriumalkanodicarboxylate der allgemeinen Formel Y2L3,nH2O mitn=3, 4, 6 bzw. 7 hergestellt. Ausgehend von den IR-Spektren konnte die Art der Koordinierung als COO− y3+ festgestellt werden. Beim Erhitzen geben Ytrriummalonat, -succinat, -glutarat, azelainat und -sebazat ihr Kristallwasser ab, aus den anhydratierten Komplexen bildet sich anschliessend Y2O3, während Yttriumadipet, pimelat und -suberat einige Wassermoleküle verlieren und die monooder dihydratierten Formen sich dann zu Y2O3 zersetzen. Die Eigenschaften der untersuchten Komplexe variieren eindeutig in Abhängigkeit davon, ob sich in der Kette eine gerade oder ungerade Anzahl von Kohlenstoffatomen befindet.
Similar content being viewed by others
References
W. W. Wendlandt, Anal. Chem., 30 (1958) 58.
W. W. Wendlandt, Anal. Chem., 31 (1958) 408.
W. W. Wendlandt, T. D. George and G. R. Morton, J. Inorg. Nucl. Chem., 17 (3–4) (1961) 273.
M. N. Ambrozy, E. F. Luchnikova and Sidorova, Zh. Neorgan. Khim., 5 (1960) 385.
J. S. Saviekaya, N. N. Tworogov et al., Zh. Neorgan. Khim., 5 (1960) 2300.
J. S. Sawickaya, N. N. Twarogov et al., Zh. Neorgan. Khim., 7 (1962) 2029.
B. S. Azikov and V. V. Serebrennikov, Voprosy Khim., 3 (1965) 72.
B. S. Azikov and V. V. Serebrennikov, Voprosy Khim., 3 (1965) 111.
P. S. Bassi and C. M. Khejuria, Thermochim. Acta, 37 (2) (1980) 173.
K. C. Patic, G. V. Chandrakelibar and H. V. George, Canad. J. Chem., 46 (2) (1968) 257.
F. J. Turova and V. V. Serebrennikov, Trudy Tomskovo Univ. Ser. Khim., 68 (1975) 264.
W. Brzyska and W. Hubicki, Annales UMCS Lublin, Sect.AA, XXIII (1968) 7.
B. S. Azikov and V. V. Serebrennikov, Zh. Neorgan. Khim., XII (2) (1967) 445.
O. E. Koblova, L. M. Vdovina and L. M. Jevgrafova, Zh. Neorgan Khim., XXII (5) (1977) 1230.
W. C. Sevostianov and L. M. Dvornikova, Zh. Neorgan Khim., XVII (6) (1972).
J. Mach and F. Brezina, Monatsh. Chem., 98 (5) (1967) 2070.
K. Huraiski et al., Bull. Chem. Soc. Japan, 6 (1982) 1845.
H. A. Nabov and B. N. Jukov, J. Thermal Anal., 30 (3) (1985) 619.
H. A. Nabov and B. N. Jukov, Bull. Chem. Soc. Japan, 58 (1985) 3582.
L. M. Vdovina and O. E. Koblova, Isled. v oblaski Khim. soedin. red. elementov (Saratov), 6 (1981) 8.
U. B. Ceipidov, G. D'ascenazo et al., Thermochim. Acta, 30 (1) (1979) 15.
C. B. Korunova, Koordin. Khim., 2 (6) (1976) 472.
A. Kwiatkowski, J. Inorg. Nucl. Chem., 34 (1972) 1583.
P. S. Bassi and C, M. Khajuria, Therchim Acta, 62 (2–3) (1985) 375.
Yoko Kuroda and Masaji Kubo, J. Phys. Chem., 64 (1960) 759.
R. C. Agrawal and A. K. Sriwastava, Indian J. Chem., 5 (12) (1967) 627.
Kh. A. Chuchas and T. P. Jezierskaya, Viesci Akad. Nauk. BSSR, (1977) 45.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Brzyska, W., Ożga, W. Preparation and properties of yttrium complexes with alkanodicarboxylic acids. Journal of Thermal Analysis 36, 441–453 (1990). https://doi.org/10.1007/BF01914498
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF01914498