Conclusion
The materials studied have their absorption edges in the visible region. The substitution of vanadium for tantalum leads to the shift of the absorption edge towards lower energies. With decreasing temperature, the absorption edge is shifted towards higher energies.
Spectral dependence of the absorption edge can be, at higher values of the absorption coefficient (K > 101cm−1), approximated by an exponential function. The absorption edge of Tl3TaS4 in the temperature interval studied can be described with the help of the Urbach rule. In the case of Tl3VS4 the absorption edge is distorted due to impurities present.
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References
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The autor would like to thank Dr. Milena Závětová, CSc. for valuable comments on the manuscript.
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Čermák, K. Optical absorption edge of Tl3VS4 and Tl3TaS4 . Czech J Phys 34, 88–93 (1984). https://doi.org/10.1007/BF01590484
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DOI: https://doi.org/10.1007/BF01590484