Skip to main content
Log in

An exactly solvable model for coherent and incoherent exciton motion

  • Published:
Zeitschrift für Physik A Hadrons and nuclei

Abstract

We treat the motion of a Frenkel exciton using a Hamiltonian which comprises a completely coherent part and a fluctuating part which describes both fluctuations of the energy of a localized exciton and fluctuations of the transition matrix elements between different lattice sites. Under the assumption that the fluctuating forces are Markoffian and Gaussian we derive exactly a density matrix equation which can be solved by a Green's function method.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Haken, H.: Fortschr. Physik6, 271 (1958).

    Article  ADS  MathSciNet  Google Scholar 

  2. Wolf, H. C.: In Solid State Phys.9, 1 (1959) (eds. F. Seitz, D. Turnbull).

  3. Davydov, A. S.: Theory of molecular excitons. New York-San Francisco-Toronto-London: McGraw Hill Book Co. Inc. 1962.

    Google Scholar 

  4. Knox, R. S.: Theory of excitons, Solid State Phys., Suppl.5, (1963).

  5. Physics and chemistry of the organic solid state, eds. D. Fox, M. M. Labes, A. Weissberger. New York-London-Sidney: Interscience Publishers 1967.

    Google Scholar 

  6. Stepanow, D. I., Gribkovskii, V. P.: Theory of luminescence. London: Illiffe Books Ltd. 1968.

    Google Scholar 

  7. Merrifield, R. E.: J. Chem. Phys.28, 647 (1958).

    Article  ADS  Google Scholar 

  8. Trlifaj, M.: Czech. J. Phys.8, 510 (1958).

    Article  ADS  MathSciNet  Google Scholar 

  9. Avakian, P., Ern, V., Merrifield, R. E., Suna, A.: Phys. Rev.165, 974 (1968).

    Article  ADS  Google Scholar 

  10. Haken, H., Strobl, G.: In: The triplet state, ed. A. B. Zahlan. Cambridge: University Press 1967.

    Google Scholar 

  11. Maier, G., Wolf, H. C.: Z. Naturforsch.23, 1068 (1968).

    ADS  Google Scholar 

  12. Schwoerer, M., Wolf, H. C.: Mol. Cryst.3, 177 (1967).

    Article  Google Scholar 

  13. Kolb, H., Wolf, H. C., Z. Naturforsch:27a, 51 (1972).

    ADS  Google Scholar 

  14. Haarer, D., Wolf, H. C.: Mol. Cryst.10, 359 (1970).

    Article  Google Scholar 

  15. Port. H., Wolf, H. C.: To be published.

  16. Era, V., Suna, A., Tomkiewicz, Y., Avakian, P., Groff, R. P.: Phys. Rev. B5, 3233 (1972).

    ADS  Google Scholar 

  17. Haken, H., Reineker, P.: Z. Physik249, 253 (1972).

    Article  ADS  Google Scholar 

  18. Reineker, P., Haken, H.: Z. Physik250, 300 (1972).

    Article  ADS  Google Scholar 

  19. Reineker, P.: Phys. stat. sol. (b)52, 439 (1972).

    Article  ADS  Google Scholar 

  20. Grover, M., Silbey, R.: J. Chem. Phys.54, 4843 (1971). A very similar equation has been derived in the meantime by Grover and Silbey, who use an explicit model for theh's. The main deficiency of that treatment is, that it does not include local scattering (i.e.γ0), which is clearly needed to explain the experimental data.

    Article  ADS  Google Scholar 

  21. Schwarzer, E., Haken, H.: Phys. Lett.42A, 317 (1972) and to be published.

    Article  ADS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Haken, H., Strobl, G. An exactly solvable model for coherent and incoherent exciton motion. Z. Physik 262, 135–148 (1973). https://doi.org/10.1007/BF01399723

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01399723

Navigation