Summary
The structures of two crystallographically independent molecules of the homohinuclear complex derived from the reaction ofN,N′-ethvlenebis(salicylideneiminato)copper(II) and bis(1,1,1,5,5,~-hexafluoropentane-2,4-(dionato)copper(II) have been determined. In each molecule, the copper atom in the Schiff base is in a square planar and that in the diketone complex in a tetragonally distorted octahedral environment respectively.
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References
C. A. Bear, J. M. Waters and T. N. Waters.J. Chem. Soc. Dalton Trans., 1059 (1974).
J. M. Epstein, B. N. Figgis, A. H. White and A. C. Willis,J. Chem. Soc. Dalton Trans., 1954 (1974).
D. E. Fenton, N. Bresciani-Pahor. M. Calligaris, G. Nardin and L. Randaccio,J. Chem. Soc. Chem. Comm., 39 (1979).
F. H. Moore,Acta Crystallogr., 16, 1169 (1963).
J. M. Stewart, F. A. Kundell and J. C. Baldwin,The X-Ray System, Computer Science Center of Maryland, College Park, U.S.A. (1970).
N. B. O'Bryan, T. O. Maier, I. C. Paul and R. S. Drago,J. Am. Chem. Soc., 95, 6640 (1973).
M. V. Veidis, G. H. Schreiber, T. E. Gough and G. J. Palenik,J. Am. Chem. Soc., 91, 1859 (1969).
J. Pradilla-Sorzano and J. P. Fackler, Jr.,Inorg. Chem., 12, 1174 (1973).
M. R. Truter and B. L. Vickery,J. Chem. Soc. Dalton Trans., 395 (1972).
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Bresciani-Pahor, N., Calligaris, M., Nardin, G. et al. The x-ray crystal structure of bis(1,1,1,5,5,5-hexafluoropentane-2,4dionato)copper(II)-N,N′-ethylenebis(salicylideneaminato)copper(II). Transition Met Chem 5, 180–183 (1980). https://doi.org/10.1007/BF01396906
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DOI: https://doi.org/10.1007/BF01396906