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Extraction and separation of bismuth(III) from steel and bismuth-base alloys

Extraktion und Trennung von Wismut(III) aus Stahl und wismuthältigen Legierungen

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Summary

Separation of bismuth(III) from iron(III), molybdenum(VI), vanadium(V), chromium(VI), titanium(IV), antimony(III), lead(II), beryllium(II), uranium(VI), hafnium(IV), indium(III) and zirconium (IV) is achieved by solvent extraction with high molecular weight amines from sodium succinate solution adjusted to suitable pH. Bismuth(III) is stripped from the organic phase and determined spectrophotometrically. The method is shown to be applicable to bismuth alloys.

Zusammenfassung

Wismut(III) läßt sich von Fe(III), Mo(VI), V(V), Cr(VI), Ti(IV), Sb(III), Pb(II), Be(II), U(VI), Hf(IV), In(III) und Zr(IV) durch Extraktion mit hochmolekularen Aminen aus Natriumsuccinat bei geeignetem pH trennen. Bi(III) wird dann von der organischen Phase getrennt und spektralphotometrisch bestimmt. Das Verfahren eignet sich für Wismutlegierungen.

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Shete, S.D., Shinde, V.M. Extraction and separation of bismuth(III) from steel and bismuth-base alloys. Mikrochim Acta 82, 63–67 (1984). https://doi.org/10.1007/BF01202162

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  • DOI: https://doi.org/10.1007/BF01202162

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