Abstract
Retention indices and dI/dT values were obtained for members of six homologous and six pseudohomologous series of polyfluorinated saturated carboxylic esters on capillary columns with OV-101 or XE-60 as stationary phase. There was a nonlinear dependence of retention indices of fluorinated fatty acid esters on carbon chain length of homologs with m, n=1–6. A universal correlation equation was shown to describe the chromatographic behavior of polyfluorinated carboxylic esters.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1740–1745, August, 1991.
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Promyshlennikova, E.P., Kirichenko, V.E., Pashkevich, K.I. et al. Capillary chromatography of polyfluorinated carboxylic esters. Russ Chem Bull 40, 1541–1545 (1991). https://doi.org/10.1007/BF01172246
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DOI: https://doi.org/10.1007/BF01172246