Skip to main content
Log in

Exploitation of a pulsed neutron source for the structural study of anisotropic polymer films

  • Papers
  • Published:
Journal of Materials Science Aims and scope Submit manuscript

Abstract

A novel but simple time-of-flight neutron scattering geometry which allows structural anisotropy to be probed directly, simultaneously and thus unambiguously in polymeric and other materials is described. A particular advantage of the simultaneous data collection when coupled to the large area of the beam is that it enables thin films (< 10 μm < 10 mg) to be studied with relative ease. The utility of the technique is illustrated by studies on both deformed poly(styrene) glasses and on thin films of electrical conducting polymers. In the latter case, the power of isotopic substitution is illustrated to great effect. The development of these procedures for use in other areas of materials science is briefly discussed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. G. Kostorz (ed). “Neutron Scattering 15: Treatise on Materials Science and Technology” (Academic, New York, 1979).

    Google Scholar 

  2. S. W. Lovesey, “Theory of Thermal Neutron Scattering” Vols 1 & 2 (Oxford University Press, Oxford, 1985).

    Google Scholar 

  3. G. L. Squires, “Introduction to the Theory of Thermal Neutron Scattering” (Cambridge University Press, Cambridge, 1978).

    Google Scholar 

  4. R. Newport, B. D. Rainford andR. Cywinski, “Neutron Scattering at a Pulsed Source” (Adam Hilger, Bristol, 1987).

    Google Scholar 

  5. C. G. Windsor, “Pulsed Neutron Scattering” (Taylor & Francis, London, 1981).

    Google Scholar 

  6. D. M. Sadler, in “Comprehensive Polymer Science” edited by C. Booth & C. Price (Pergamon, Oxford, 1989) ch. 32.

    Google Scholar 

  7. A. C. Wright, in “Advances in Structure Research by Diffraction Methods” edited by W. Hoppe & R. Mason (Pergamon, Oxford, 1974) p. 1.

    Google Scholar 

  8. G. R. Mitchell, in “Comprehensive Polymer Science” edited by C. Booth & C. Price (Pergamon, Oxford, 1989) ch. 31.

    Google Scholar 

  9. G. R. Mitchell andR. Lovell,Acta Cryst. A37 (1981) 189.

    Google Scholar 

  10. O. Vogel, “Textbook of Practical Organic Chemistry” 4th edn. (Longman, London, 1978) p. 642.

    Google Scholar 

  11. H. Tadokoro, “Structure of Crystalline Polymers” (Wiley Interscience, New York, 1979) p. 199.

    Google Scholar 

  12. G. R. Mitchell andA. H. Windle,Colloid Polym. Sci. 260 (1982) 754.

    Google Scholar 

  13. W. S. Howells,J. Phys. 45 (1984) 81.

    Google Scholar 

  14. Rutherford Appleton Laboratory Report RAL-90-041 “User Guide to Experimental Facilities at ISIS” (Rutherford Application Laboratory, Chilton, Didcot, Oxon, U.K. 1990).

  15. R. Cywinski, Rutherford Appleton Laboratory Report NDR/P15/83 (Rutherford Appleton Laboratory, Chilton, Didcot, Oxon, U.K. 1983).

    Google Scholar 

  16. G. R. Mitchell andA. H. Windle,Polymer 25 (1984) 906.

    Google Scholar 

  17. “Handbook of Conducting Polymers” edited T. A. Skotheim (Dekker, New York, 1986).

    Google Scholar 

  18. G. R. Mitchell,Polym. Commun. 27 (1986) 346.

    Google Scholar 

  19. G. R. Mitchell andA. Geri,J. Phys. D: Appl. Phys. 20 (1987) 1346.

    Google Scholar 

  20. G. R. Mitchell, F. J. Davis, R. Cywinski andW. S. Howells,J. Phys. C: Solid State Phys. 21 (1988) L411.

    Google Scholar 

  21. S. M. Wecker, T. Davidson andJ. B. Cohen,J. Mater. Sci. 7 (1972) 1249.

    Google Scholar 

  22. B. Rosi, G. R. Mitchell andA. K. Soper, submitted ToPolym. Commun.

  23. G. R. Mitchell, F. J. Davis andC. H. Legge,Synthetic Metals 26 (1988) 247.

    Google Scholar 

  24. G. R. Mitchell, F. J. Davis, R. Cywinski andA. C. Hannon,Polym. Commun. 30 (1989) 98.

    Google Scholar 

  25. P. G. De Gennes,C.R. Acad. Sci. (Paris) 274 (1972) 142.

    Google Scholar 

  26. G. R. Mitchell andA. H. Windle,Polymer 24 (1983) 1513.

    Google Scholar 

  27. G. R. Mitchell andA. H. Windle, in “Crystalline Polymers” edited by D. C. Bassett (Elsevier, London, 1988) Chap. 3.

    Google Scholar 

  28. R. Pynn,J. Phys. Chem. 34 (1973) 735.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Mitchell, G.R., Cywinski, R. Exploitation of a pulsed neutron source for the structural study of anisotropic polymer films. J Mater Sci 27, 2117–2123 (1992). https://doi.org/10.1007/BF01117925

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01117925

Keywords

Navigation