Conclusions
-
1.
A four-stage reaction has been developed for the synthesis of 4-alkyl(cycloalkyl, phenyl)thiacyclohexanes, starting from α-olefins.
-
2.
The new compounds 4-hexyl-, 4-phenyl- and 4-cyclohexylthiacyclohexane and the corresponding sulfones have been prepared.
Similar content being viewed by others
Literature cited
E. V. Whitehead, R. A. Dean, and F. A. Fidler, J. Am. Chem. Soc.,73, 3632 (1951).
C. R. Johnson and D. McCants, Jr., J. Am. Chem. Soc.,87, 1109 (1965).
R. Onesta and G. Castelfranehi, Gazz. Chim. Ital.,89, 1127 (1959).
F. Straus and W. Thiel, Liebigs Ann. Chem.,525, 151 (1936).
C. D. Nenitzescu and V. Przemetski, Ber.,69, 2706 (1936).
Sh. Mamedov, Zh. Obshch. Khim.,27, 1499 (1957).
Sh. Mamedov and D. N. Khydyrov, Zh. Obsh. Khim.,31, 3905 (1961).
M. V. Likhosherstov and S. V. Alekseev, Zh. Obshch. Khim.,4, 1280 (1934).
P. E. Peterson and F. J. Slama, J. Org. Chem.,35, 529 (1970).
Yu. K. Yur'ev, Practical Organic Chemistry [in Russian], Coll. 1 and 2, Izd. Mosk. Univ. (1961), p. 223.
N. P. Volynskii, L. P. Shcherbakova, and G. D. Gal'pern, Izv. Akad. Nauk SSSR, Ser. Khim., 2299 (1976).
C. Weygand and G. Hilgetag, Methods of Experimental Organic Chemistry [Russian translation], Khimiya (1968), p. 612.
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1077–1080, May, 1979.
Rights and permissions
About this article
Cite this article
Volynskii, N.P., Shcherbakova, L.P. Synthesis of 4-substituted thiacyclohexanes. Russ Chem Bull 28, 1006–1009 (1979). https://doi.org/10.1007/BF00963317
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00963317