Conclusions
The mechanisms were studied for the fragmentation of methyl-, ethyl-, propylcyclobutanes, and pinane upon electron impact by means of the selective deuteration of unsaturated cyclobutane hydrocarbons in the inlet system of a mass spectrometer.
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Literature cited
A. I. Mikaya, V. I. Stepanin, V. G. Zaikin, and V. M. Vdovin, Izv. Akad. Nauk SSSR, Ser. Khim., 581 (1985).
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V. G. Zaikin, A. I. Mikaya, and V. M. Vdovin, The Mass Spectrometry of Small Carbon, Silicon, and Germanium Rings [in Russian], Nauka, Moscow (1983).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2405–2408, October, 1985.
The authors express their gratitude to E. B. Portnykh for the samples of methylenecyclobutane andβ-pinene and to A. B. Amerik for the samples of vinyl- and propenylcyclobutanes.
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Mikaya, A.N., Romanov, G.D., Zaikin, V.G. et al. Deuteration in a chromato-mass spectrometer inlet system in a study of the fragmentation mechanisms of cyclobutane hydrocarbons. Russ Chem Bull 34, 2228–2231 (1985). https://doi.org/10.1007/BF00963271
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DOI: https://doi.org/10.1007/BF00963271